Copper(I) reactions in N-heterocycle synthesis: Efficient preparation of substituted pyrrolidinones

DOI: 10.1016/S0040-4039(99)01805-5

Source and publish data:

Tetrahedron Letters p. 8615 - 8618 (1999)

Update date:2022-08-24

Topics:

Authors:

Davies, David T.

Kapur, Neha

Parsons, Andrew F.

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Article abstract of DOI:10.1016/S0040-4039(99)01805-5

Reaction of halo-enamides with copper(I) chloride in boiling toluene has been shown to produce unsaturated pyrrolidinones in excellent yield (81-94%). Both di- and trichloroamide precursors can be used to form dienes via an initial 5-endo-trig radical cyc

Full text of DOI:10.1016/S0040-4039(99)01805-5

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