Journal of Organic Chemistry p. 3808 - 3810 (1982)
Update date:2022-08-25
Topics:
Brown, Herbert C.
Basavaiah, D.
Kulkarni, Surendra U.
The hydroboration of 1-bromo-1-alkynes with alkylbromoboranes (RBHBr*SMe2), conveniently obtained via the controlled hydridation of alkyldibromoboranes (RBBr2*SMe2), followed by treatment with sodium methoxide produces B-(trans-1-alkyl-1-alkenyl)boronate esters that provide the corresponding trans alkenes on protonolysis and ketones on oxidation
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