Synthesis, characterisation, and crystal structure of a tetra(phosphino)ethene

DOI: 10.1016/0022-328X(89)88061-1

Source and publish data:

Journal of Organometallic Chemistry p. C7 - C11 (1989)

Update date:2022-08-11

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Authors:

Anderson, David M.

Hitchcock, Peter B.

Lappert, Michael F.

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Article abstract of DOI:10.1016/0022-328X(89)88061-1

The dilithio-1,2-bis(phenylphosphino)ethane reagent <(PhPCH2CH2PPh)2>2 (THF=tetrahydrofuran) reacts with C2Cl4 in THF at -50 deg C to give (I), a novel alkene with a P2C=CP2 framework, whereas Li(PPh2) and C2Cl4 under ambient condition

Full text of DOI:10.1016/0022-328X(89)88061-1

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