Alicyclic Claisen rearrangement with a two-atom ring contraction. A new synthetic approach to cembranoids

DOI: 10.1016/S0040-4039(00)60761-X

Source and publish data:

Tetrahedron Letters p. 1721 - 1724 (1993)

Update date:2022-08-11

Topics:

Authors:

Petasis Petasis

Bzowej Bzowej

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)60761-X

Methylenation of certain olefinic lactones with dimethyl titanocene, followed by thermal or triisobutylaluminium-mediated Claisen rearrangement leads to cembrane-like 11-15-membered ring ketones bearing an isopropenyl side chain.

Full text of DOI:10.1016/S0040-4039(00)60761-X

Products guided by the article

Product name:Phosphonium, (11-carboxyundecyl)triphenyl-, bromide

Cas No:73367-75-6

R&D Labs maybe for 73367-75-6

Jiangxi Global Natural Spice Co., Ltd.

website:https://www.jxhqxl.com/

Contact:+86-796-8106598

Address:No.89, Wenshan Road,South Industrial Park, Jishui County,Jiangxi Province
Suqian Ruixing Chemical Co., Ltd.

Contact:+86-527-80805666（总机）;84836008(销售)

Address:3 Jingsilu, Zone north, Hubin Xincheng Development Park, Suqian, China
Quzhou Ruiyuan chemical Co., Ltd

Contact:+86-570-3039321/3039361/3039308

Address:18# Huayang Road,Quzhou High-tech Industrial Park, Zhejiang China.
HANGZHOU TOYOND BIOTECH CO., LTD

Contact:+86-571-86965177

Address:No. 189, Fengqi East Road, Hangzhou, China
Shanghai WinTide BioTechnology Co.,Ltd

Contact:86-21-37100630

Address:No. 908 Yunhe Road, Fengxian district, Shanghai

Relevant to this article

Doi:10.1007/BF01106647
()
Anticancer activity of some newly synthesized pyrano[2,3-d][1,2,3]triazine derivatives using 1-(7-hydroxy-2,2-dimethylchroman-6-yl)ethanone as synthon

Doi:10.1007/s00044-014-1229-0
(2015)
Efficient enzymatic kinetic resolution of 4-hydroxytetralone and 3-hydroxyindanone

Doi:10.1016/S0957-4166(01)00404-9
(2001)
A new series of bipyridine based chiral organocatalysts for enantioselective Henry reaction

Doi:10.1039/c6nj01045h
(2016)
Phosphate-modified carbon nanotubes in the oxidative dehydrogenation of isopentanes

Doi:10.1002/cssc.201402457
(2014)
Synthesis of biologically active pentapeptide analogs of the N-terminal part of lipoprotein from the outer membrane of Escherichia coli

Doi:10.1248/cpb.38.1110
(1990)

Article Doi