Organometallics p. 568 - 570 (1993)
Update date:2022-08-30
Topics:
Smith, Glen D.
Hanson, Brian E.
Merola, Joseph S.
Waller, Francis J.
Bis(carbomethoxy)palladium bipyridine is synthesized by the reaction of (bipy)PdCl2 with LiOCH3 under a CO atmosphere. NMR evidence for the apparent precursor to (bipy)Pd(CO2CH3)2, i.e. (bipy)Pd(OCH3)2, was obtained in situ by NMR spectroscopy. (bipy)-Pd(CO2CH3)2 crystallizes in the monoclinic space group C2/c with a = 16.851 (10) ?, b = 12.137 (5) ?, c = 7.088 (4) ?, β = 97.99(5)°, V = 1435(1) ?3, and Z = 4. The final refinement indices are R = 0.0681 and R(w) = 0.0774. The compound is thermally stable in methanol at temperatures up to 60°C; it decomposes in THF to yield methanol, bipyridine, and palladium metal.
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