Organometallics p. 568 - 570 (1993)
Update date:2022-08-30
Topics:
Smith, Glen D.
Hanson, Brian E.
Merola, Joseph S.
Waller, Francis J.
Bis(carbomethoxy)palladium bipyridine is synthesized by the reaction of (bipy)PdCl2 with LiOCH3 under a CO atmosphere. NMR evidence for the apparent precursor to (bipy)Pd(CO2CH3)2, i.e. (bipy)Pd(OCH3)2, was obtained in situ by NMR spectroscopy. (bipy)-Pd(CO2CH3)2 crystallizes in the monoclinic space group C2/c with a = 16.851 (10) ?, b = 12.137 (5) ?, c = 7.088 (4) ?, β = 97.99(5)°, V = 1435(1) ?3, and Z = 4. The final refinement indices are R = 0.0681 and R(w) = 0.0774. The compound is thermally stable in methanol at temperatures up to 60°C; it decomposes in THF to yield methanol, bipyridine, and palladium metal.
Suzhou Wedo Chemicals Co., Ltd.
Contact:86 512 58100425
Address:Zonger Road, DongSha Industry Park , Zhangjiagang, Jiangsu, China
Shandong Xinhua Pharmaceutical Co.,Ltd
website:http://www.xhzy.com
Contact:+86-533-2196801
Address:1 lutai road,zhangdian dis,Zibo City
Wuxi Zuping Food Science And Technology Co.,LTD.
Contact:+86-510-87210822
Address:Guanlin town
Contact:+86-571-28186845
Address:Room 1224,Eastcom Mansion,398 Wensan Road,Hangzhou,310013 China
Shenyang Xingzhenghe Chemical Co., Ltd.
Contact:024-23509232
Address:No. 33, Naner Road, Heping Dist.
Doi:10.1021/j100325a022
(1988)Doi:10.1016/j.molstruc.2019.07.029
(2019)Doi:10.1002/kin.21107
(2017)Doi:10.1021/jo00211a041
(1985)Doi:10.1016/j.procbio.2017.01.006
(2017)Doi:10.1021/ic00118a005
(1995)
