Kinetics and Catalysis p. 258 - 272 (2011)
Update date:2022-08-29
Topics:
Chistyakov
Tsodikov
Murzin, V. Yu.
Yandieva
Zubavichus, Ya. V.
Kozitsyna, N. Yu.
Gekhman
Kriventsov
Moiseev
The results of the direct conversion of ethanol and its mixture with glycerol into a C4-C10+ alkane and olefin fraction in the presence of Pd-, Zn-, and Pd-Zn-containing catalysts, which were prepared by supporting homo- and heterometallic acetate complexes onto the surface of γ-Al2O3, are reported. It was found that, in the presence of mono- and bicomponent Pd-ZnO (Pd; ZnO)/γ-Al2O 3 systems, selectivity in the formation of alkanes, olefins, or their mixtures in the target fraction can be controlled as a result of the cocatalytic effect of active components that are responsible for the catalyst activity in condensation and hydrogenation reactions. The structures of the active components were studied and the genesis of the catalytic systems was characterized using XAFS, XPS, and XRD analysis. It was found that the addition of glycerol considerably increased the yield of the target hydrocarbon fraction.
View Morewebsite:http://www.sagechem.com
Contact:+86-571-86818502
Address:Room C1301, New Youth Plaza, 8 Jia Shan Road, Hangzhou, China
Contact:+86-913-2223392
Address:No. 32, Xinanjing Road, Weinan City, Shaanxi Province, 714000, China
Contact:0519-85170101-802
Address:Fifth Floor,B of Beihua Buliding,520 Road of Science and Education City,Changwu middle road NO.801,Wujin District,Changzhou,Jiangsu province
website:http://www.antimex.com
Contact:0086-21-50563169
Address:Room1027,No.Jinyu Road,Pudong
Shanghai Sunwise Chemical Co., Ltd
website:http://www.sunwisechem.com
Contact:86-021-33883180
Address:Room 10E, Building G, Westlink Center, No. 2337 Gudai Road, Minhang District, Shanghai, China PC: 201100
Doi:10.1016/j.catcom.2016.03.018
(2016)Doi:10.1016/j.jfluchem.2014.09.007
(2015)Doi:10.1080/00021369.1984.10866438
(1984)Doi:10.1002/anie.201809621
(2019)Doi:10.1002/zaac.19966220810
(1996)Doi:10.3390/molecules23061463
(2018)