Inorganic Chemistry p. 1765 - 1772 (1978)
Update date:2022-08-12
Topics:
Leung
Aubke
The synthesis of silver(II) fluorosulfate, Ag(SO3F)2, by a variety of routes is described. The preparations of a mixed-valency compound of the composition Ag3(SO3F)4 and its potassium analogue K2AgII(SO3F)4, the compounds AgIIPtIV(SO3F)6 and AgIISnIV(SO3F)6, and the complex [Ag(bpy)2](SO3F)2 are also reported. Structural studies are based on vibrational, electronic mull and diffuse reflectance, and ESR spectra as well as magnetic susceptibility measurements in the temperature range of 80 to about 300 K. Both Ag3(SO3F)4 and K2Ag(SO3F)4 show antiferromagnetic coupling. All other divalent silver compounds synthesized here are magnetically dilute with the Ag2+ ion in a square-planar or tetragonally distorted (elongated) octahedral environment.
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Doi:10.1021/ja01321a016
(1934)Doi:10.1007/BF03020428
()Doi:10.1016/0008-6215(95)00203-6
(1995)Doi:10.1021/acs.inorgchem.8b01733
(2018)Doi:10.1016/S0022-328X(00)98078-1
(1977)Doi:10.1002/anie.201710186
(2017)
