Inorganic Chemistry p. 1765 - 1772 (1978)
Update date:2022-08-12
Topics:
Leung
Aubke
The synthesis of silver(II) fluorosulfate, Ag(SO3F)2, by a variety of routes is described. The preparations of a mixed-valency compound of the composition Ag3(SO3F)4 and its potassium analogue K2AgII(SO3F)4, the compounds AgIIPtIV(SO3F)6 and AgIISnIV(SO3F)6, and the complex [Ag(bpy)2](SO3F)2 are also reported. Structural studies are based on vibrational, electronic mull and diffuse reflectance, and ESR spectra as well as magnetic susceptibility measurements in the temperature range of 80 to about 300 K. Both Ag3(SO3F)4 and K2Ag(SO3F)4 show antiferromagnetic coupling. All other divalent silver compounds synthesized here are magnetically dilute with the Ag2+ ion in a square-planar or tetragonally distorted (elongated) octahedral environment.
Hangzhou Gangjin Chemical Co.,Ltd.(expird)
Contact:+86-571-85109780
Address:707 Zhejiang Minhang Bldg., No.290 Zhongshan North Road, Hangzhou 310003, China
Suzhou Health Chemicals Co., Ltd.
website:http://www.healthchems.com
Contact:13776257979
Address:No. 338, Jingang Avenue,
Shanghai Forever Biotech Co., Ltd.
Contact:+86-21-69734790
Address:Room 5017/5019、5022、5024 of Technology Innovation Centre, No.1155, Gongyuan East Rd, QingPu District, Shanghai China.
Shanghai Longjin Metallic Material Co., Ltd.
website:http://www.shlongjin.cn/
Contact:021-56517503,56502257
Address:No.16, Lane 555, Chengyin Road, Shanghai
website:http://www.shtopchem.com/
Contact:0086-0576-87776998
Address:room no 1608,xuhui business building yude road,xujiahui street, xuhui district
Doi:10.1021/ja01321a016
(1934)Doi:10.1007/BF03020428
()Doi:10.1016/0008-6215(95)00203-6
(1995)Doi:10.1021/acs.inorgchem.8b01733
(2018)Doi:10.1016/S0022-328X(00)98078-1
(1977)Doi:10.1002/anie.201710186
(2017)
