Journal of Physical Chemistry p. 10582 - 10586 (1991)
Update date:2022-08-11
Topics:
Hop, C. E. C. A.
McMahon, T. B.
The gas-phase bimolecular nucleophilic substitution reactions Br- + CCl4 -> BrCCl3 + Cl-, Br- + CF2Cl2 -> BrCF2Cl + Cl-, and Cl- + CBr4 -> ClCBr3 + Br- were studied as a function of the center-of-mass energy with Fourier transform ion cyclotron resonance spectrometry.From the energy dependence and the threshold energies of these reactions, conclusions were drawn concerning the mechanism involved.
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