Journal of Organometallic Chemistry p. 249 - 255 (1980)
Update date:2022-08-30
Topics:
Dolgoplosk, B. A.
Tinyakova, E. I.
Guzman, I. Sh.
Vollerstein, E. L.
Chigir, N. N.
et al.
It has been established that in the interaction of NdCl3 and YCl3 with RLi, where R=CH2C6H5, CH2C(CH3)2C6H5, CH2Si(CH3)3, unusual organometallic compounds are formed.They are stable in hydrocarbon solutions.The benzyl and neophyl derivatives are carbene type complexes containing one R group at a trivalent metal atom.In all cases the reaction is accompanied by the evolution of RH as the main product and some stilbene and tolan when R=CH2C6H5.The mechanism of this reaction is discussed.
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Doi:10.1039/a703506c
(1998)Doi:10.1021/jacs.8b12331
(2019)Doi:10.1021/ja01152a501
(1951)Doi:10.1002/hc.20094
(2005)Doi:10.1039/c39880001317
(1988)Doi:10.1021/acs.orglett.0c04130
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