A COMPARISON OF FACE-CAPPING VERSUS FRAGMENTATION REACTIONS OF WITH triphos, (MeC(CH2PPh2)3 AND TRIPOD, (HC(PPh2)3); CRYSTAL STRUCTURE OF

DOI: 10.1016/0022-328X(87)80135-3

Source and publish data:

Journal of Organometallic Chemistry p. C19 - C22 (1987)

Update date:2022-08-16

Topics:

Authors:

Allevi, Claudio

Golding, Martin

Heaton, Brian T.

Ghilardi, Carlo A.

Midollini, Stefano

Orlandini, Annabella

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Article abstract of DOI:10.1016/0022-328X(87)80135-3

The initial reaction of with triphos results in either face-capping or fragmentation reactions which occur at different temperatures whereas only face-capping occurs with tripod; the fragmentation products further react with triphos, but not with tripod, to give <(triphos)Rh(μ-CO)2Rh(triphos)> which has been structurally characterised by X-ray crystallography.

Full text of DOI:10.1016/0022-328X(87)80135-3

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