Journal of Organometallic Chemistry p. 303 - 309 (1981)
Update date:2022-07-30
Topics:
Battoni, Jean-Paul
Dupre, Daniel
Mansuy, Daniel
Reduction of trichloromethyltrimethylsilane by ferrotetraarylporphyrins, FeII(P), in the presence of an excess of a reducing agent, leads to the formation, of a reducing agent or of Fe(P)(CS) complexes when sodium dithionite is used as a reducing agent.These results can be explained by the involvement of unstable α-silylcarbeneferroporphyrin complexes.
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