Deuterium-exchange reaction in a CF3CHBrCl-D2O two-liquid phase system

DOI: 10.1016/S0022-1139(00)82840-7

Source and publish data:

Journal of Fluorine Chemistry p. 285 - 292 (1992)

Update date:2022-08-11

Topics:

Authors:

Ogata, Yukio

Sugihara, Kei-ichi

Sakka, Tetsuo

Iwasaki, Matae

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Article abstract of DOI:10.1016/S0022-1139(00)82840-7

An alkali-catalyzed hydrogen isotope exchange reaction was studied in a CF3CHBrCl-D2O two liquid phase system.The exchange rate was comparable to that in the CHCl3-D2O system previously recognized as the system having the highest exchange rate under alkaline conditions.It was confirmed that CF3CHBrCl was resistant to decomposition caused by alkali.These properties indicate that CF3CHBrCl could be a candidate for a working material in laser hydrogen-isotope separation processes.

Full text of DOI:10.1016/S0022-1139(00)82840-7

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