Tetrahedron Letters p. 9735 - 9738 (1998)
Update date:2022-08-11
Topics:
Fujisawa, Tamotsu
Ito, Takatoshi
Nishiura, Shin
Shimizu, Makoto
A novel alkylating ring cleavage reaction of enantiomerically pure β- trichloromethyl-β-propiolactone as a chiral building block with organoaluminum compounds provided ring-opened products with a chiral trichloromethyl carbinol moiety. A product was demonstrated to be used as an effective chiral synthon for the synthesis of chiral bioactive derivatives such as ipsdienol and sodium cilastatin.
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