Pteridines. 48. Utilization of 3,3-Dimethoxy-2-pyrrolidinopropene for the Synthesis of Folic Acid, N2'-Acetyl-7-folic Acid, and 5-Deaza-7-folic Acid

DOI: 10.1021/jo00320a034

Source and publish data:

Journal of Organic Chemistry p. 1394 - 1402 (1981)

Update date:2022-08-05

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Authors:

Taylor, Edward C.

Dumas, Donald J.

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Article abstract of DOI:10.1021/jo00320a034

3,3-Dimethoxy-2-pyrrolidinopropene (7) is shown to be a useful intermediate for the synthesis of 6-formylpterin (1), 7-formylpterin (8), and 5-deaza-7-formylpterin (9).Thus, treatment of 7 with nitrosyl chloride followed by hydrolysis gives 1,1-dimethoxy-

Full text of DOI:10.1021/jo00320a034

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