FACILE PHOTOGENERATION OF COORDINATIVELY UNSATURATED ACTIVE SPECIES FROM HYDRIDOPHOSPHONITECOBALT(I) COMPLEX AND ITS APPLICATION TO DOUBLE-BOND MIGRATION OF OLEFIN

Article abstract of DOI:10.1246/cl.1983.261

Pyrex-filtered irradiation of thermally inert complex 4> dissociated PPh(OMe)2 from cobalt without cleavage of a hydrido-cobalt bond, yielding an active species "CoH3".The photogenerated species caused double-bond migration of 3-phenylpropene to (E)- and (Z)-1-phenylpropenes.