FACILE PHOTOGENERATION OF COORDINATIVELY UNSATURATED ACTIVE SPECIES FROM HYDRIDOPHOSPHONITECOBALT(I) COMPLEX AND ITS APPLICATION TO DOUBLE-BOND MIGRATION OF OLEFIN

DOI: 10.1246/cl.1983.261

Source and publish data:

Chemistry Letters p. 261 - 264 (1983)

Update date:2022-08-23

Topics:

Authors:

Onishi, Masayoshi

Hiraki, Katsuma

Matsuda, Masahiko

Fukunaga, Tetsuo

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Article abstract of DOI:10.1246/cl.1983.261

Pyrex-filtered irradiation of thermally inert complex 4> dissociated PPh(OMe)2 from cobalt without cleavage of a hydrido-cobalt bond, yielding an active species "CoH3".The photogenerated species caused double-bond migration of 3-phenylpropene to (E)- and (Z)-1-phenylpropenes.

Full text of DOI:10.1246/cl.1983.261

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