Journal of Organic Chemistry p. 5727 - 5731 (1985)
Update date:2022-08-16
Topics:
Mundy, Bradford P.
Wilkening, David
Lipkowitz, Kenneth B.
A new approach to the natural propellane modhephene is described.Critical to the success of this synthesis was a dianion-mediated cyclopentannulation procedure, a heteroatom-assisted stereoselective hydrogenation, a regioselective lactonization, and a dimethylation of a carbonyl.
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Doi:10.1016/S0040-4039(01)90852-4
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