Tetrahedron Letters p. 2459 - 2462 (1981)
Update date:2022-08-17
Topics:
Matz, James R.
Cohen, Theodore
In the presence of acid, 2-alkyl-2-vinylcyclobutanones rearrange mainly by a 1,2-acyl migration to give cyclopentenones while 2-vinylcyclobutanones lacking 2-alkyl substituents undergo a 1,3-acyl migration to produce cyclohexenenes: the former rearrangement can be used to produce angularly substituted fused bicyclic systems.
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