Kinetics of Electrophilic Alkylations of Barbiturate and Thiobarbiturate Anions

DOI: 10.1021/acs.joc.7b01223

Source and publish data:

Journal of Organic Chemistry p. 8476 - 8488 (2017)

Update date:2022-08-16

Topics:

Authors:

Schade, Alexander

Tchernook, Ivan

Bauer, Mirko

Oehlke, Alexander

Breugst, Martin

Friedrich, Joachim

Spange, Stefan

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Article abstract of DOI:10.1021/acs.joc.7b01223

Second-order rate constants (k₂) of the reactions of various barbiturate anions such as the parent barbiturate, 1,3-dimethylbarbiturate, 2-thiobarbiturate, and 1,3-diethyl-2-thiobarbiturate with diarylcarbenium ions and Michael acceptors have b

Full text of DOI:10.1021/acs.joc.7b01223

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