
Journal of Chemical Physics p. 394 - 400 (1990)
Update date:2022-08-17
Topics:
Schlie, L. A.
Wright, M. W.
The behaviour of electron beam initiated discharges in HN3 and inert gas mixtures for different E/N values are presented.These results are the first reported investigations of this highly energetic azide gas under plasma conditions.Using a 3 ns. 600 KeV ionizing electron beam, the temporal decay of the discharge current shows HN3 is electronegative.HN3 attachment rate constants in Ar are 5.0-10.0x10-11 cm3 s-1 for E/N values in the range 1-4 Td (10-17 V cm2).With the other inert gases (He, Ne, Kr, and Xe), HN3 attachment rate constants are 0.5-4.5x10-10cm3 s-1 for the E/N range of 0.5-7.0 Td.Plasma excitation of Ar and HN3 gas mixtures produce intense N2(C -> B, υ' = 0 -> υ'' = 0) electronic transition radiation at 3371 Angstroem.
Chemvon Biotechnology Co. Ltd.
website:http://www.chemvon.com
Contact:86-21-58550039;86-21-31268550-8004
Address:Suite B-10#, 6999 Chuansha Road, Pudong District, Shanghai 201202, China
Nanjing lanbai chemical Co.,Ltd.
Contact:+86-25-85499326
Address:Room 908, 9F Taiyue Building,No.285 Heyan Road
Shenzhen ZheYi Chemicals Co.,LTD(Shanghai Branch)
Contact:+86-21-54159691
Address:Room1002,Building No.2, Lane 98 Bixiu Road,Minhang District, Shanghai,China 201100
WUHU HUAHAI BIOLOGY ENGINEERING CO LTD
Contact:+86-553-3836920
Address:7/F NO.82 LAODONG ROAD WUHU CHINA
Beijing Green Guardee Technology CO,.LTD
Contact:+86-10-69706062
Address:F2 BLdj,5 No.37 Chaoqian Road
Doi:10.1063/1.98987
(1987)Doi:10.1016/0022-1902(70)80218-4
(1970)Doi:10.1016/0040-4020(67)85009-9
(1967)Doi:10.1002/anie.201002763
(2010)Doi:10.1021/acs.jmedchem.7b00846
(2017)Doi:10.1021/ac60106a016
(1955)