
Journal of Chemical Physics p. 394 - 400 (1990)
Update date:2022-08-17
Topics:
Schlie, L. A.
Wright, M. W.
The behaviour of electron beam initiated discharges in HN3 and inert gas mixtures for different E/N values are presented.These results are the first reported investigations of this highly energetic azide gas under plasma conditions.Using a 3 ns. 600 KeV ionizing electron beam, the temporal decay of the discharge current shows HN3 is electronegative.HN3 attachment rate constants in Ar are 5.0-10.0x10-11 cm3 s-1 for E/N values in the range 1-4 Td (10-17 V cm2).With the other inert gases (He, Ne, Kr, and Xe), HN3 attachment rate constants are 0.5-4.5x10-10cm3 s-1 for the E/N range of 0.5-7.0 Td.Plasma excitation of Ar and HN3 gas mixtures produce intense N2(C -> B, υ' = 0 -> υ'' = 0) electronic transition radiation at 3371 Angstroem.
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