Molecular-beam mass spectrometry of van der Waals clusters. Mass spectrum of hydrogen sulfide dimer

Article abstract of DOI:10.1007/BF00696907

Hydrogen sulfide clusters generated by ultrasonic expansion of an H2S-Ar mixture into a vacuum were detected by electron impact mass spectrometry.The mass spectrum of the dimer, (H2S), was obtained under conditions of predominant dimerization.A mechanism of the formation of ions that involves intracluster reactions between the fragment ions of the monomer and the monomer molecule has been suggested.