
Journal of the American Chemical Society p. 1754 - 1757 (1987)
Update date:2022-08-17
Topics:
Appelman, Evan H.
Jache, Albert W.
Passage of F2 over ice at temperatures around -50 deg C produces a mixture of O2, HOF, and OF2, along with small amounts of H2O2.The involvement of HOF in the formation of OF2 has been demonstrated through the use of HOF labeled both with 18O and with radioactive 18F.The reaction that produces the OF2 has been shown to be F2 + HOF -> OF2 + HF.The OF2 contains one fluorine atom from the F2 and one from the HOF.
Doi:10.1021/ja01004a056
(1968)Doi:10.1016/j.ejmech.2014.10.005
(2014)Doi:10.1039/C39790000316
(1979)Doi:10.1016/j.saa.2013.07.074
(2014)Doi:10.1016/j.bmcl.2020.127225
(2020)Doi:10.1002/jccs.201500281
(2016)