Metallocen-Chemie hochfluorierter Ligand-Systeme XII. Synthese und Charakterisierung von Cp2Ti(BiF6)2

Article abstract of DOI:10.1016/0022-328X(90)87187-I

The preparation of the first fluorine-coordinated metallocene hexafluorobismuthate complex is reported.Cp2Ti(BiF6)2 (1) was prepared from the reaction of Cp2TiF2 with BiF5 in SO2ClF in the presence of anhydrous HF, followed by recrystallization of 1 from