Journal of Solid State Chemistry p. 83 - 88 (1979)
Update date:2022-08-12
Topics:
Petrov
Kofstad
The electrical conductivity and ionic transport number of CaMoO//4 has been measured as a function of the partial pressure of oxygen (1-10** minus **1 **8 atm) at 750, 800, and 850 degree C. Two sets of samples were studied: (1) CaMoO//4 annealed at 1100 degree C in the presence of CaO, and (2) CaMoO//4 annealed in MoO//3 vapor at 1100 degree C. Sample 1 is a mixed ionic/electronic conductor while Sample 2 is essentially an electronic conductor. A defect structure model is proposed to explain the results.
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