Reduction of III(tfpp)Cl> by Azaferrocene. The Crystal Structure of II(tfpp)2>

DOI: 10.1039/DT9920003059

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3059 - 3060 (1992)

Update date:2022-08-17

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Authors:

Zakrzewski, Janusz

Cesario, Michele

Guilhem, Jean

Giannotti, Charles

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Article abstract of DOI:10.1039/DT9920003059

Azaferrocene reacts with chloro<5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato>iron(III) to give a low-spin iron(II) porphyrin, II(tfpp)2>, the crystal and molecular structure of which has been determined; while air-stable in the solid state, in solution it loses co-ordinated azaferrocene and (under aerobic conditions) undergoes oxidation to Fe^III.

Full text of DOI:10.1039/DT9920003059

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