Tetrahedron p. 5039 - 5046 (1984)
Update date:2022-08-17
Topics:
Guay, Vincent
Brassard, Paul
A new diene, 1,2-dimethoxy-1-trimethylsiloxy-1,3-pentadiene, has been prepared from crotonaldehyde via the cyanohydrin and the β,γ-unsaturated ester.The usefulness of the reagent is demonstrated by advantageous syntheses of the naturally occurring title-compounds and of various partially methylated analogues.The electron-donating substituents on the diene are disposed in order to illustrate the consequence of their oppossing electronic effects.
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Doi:10.1007/BF00950578
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