Stereoselectivity in ene reactions with 1O2: Matrix effects in polymer supports, photo-oxygenation of organic salts and asymmetric synthesis

Article abstract of DOI:10.1562/2006-03-03-RA-832

The ene reaction of chiral allylic alcohols is applied as a tool for the investigation of intrapolymer effects by means of the stereoselectivity of the singlet-oxygen addition. The diastereo selectivity strongly depends on the structure of the polymer, th