Preparation and reactions of allenic zirconium species from propargylic ether derivatives

DOI: 10.1016/0040-4039(92)80020-K

Source and publish data:

Tetrahedron Letters p. 3769 - 3772 (1992)

Update date:2022-08-16

Topics:

Authors:

Ito Ito

Nakamura

Taguchi Taguchi

Hanzawa Hanzawa

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Article abstract of DOI:10.1016/0040-4039(92)80020-K

The generation of allenic zirconium intermediates by treating propargylic ether derivatives with 'Cp₂Zr' and their reactions with aldehydes in the presence of borontrifluoride etherate yield anti-β-acetylenic alcohols along with α-allenic alcohols.

Full text of DOI:10.1016/0040-4039(92)80020-K

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