SILICON IN ORGANIC SYNTHESIS. 14. FIVE RING ANNULATION PROCESSES BASED UPON THERMAL REARRANGEMENT OF (1-TRIMETHYLSILYLCYCLOPROPYL)ETHYLENES

DOI: 10.1016/S0040-4039(00)86804-5

Source and publish data:

Tetrahedron Letters p. 263 - 266 (1982)

Update date:2022-08-30

Topics:

Authors:

Paquette, Leo A.

Wells, Gregory J.

Horn, Keith A.

Yan, Tu-Hsin

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Article abstract of DOI:10.1016/S0040-4039(00)86804-5

Pyrolysis of (1-trimethylsilylcyclopropyl)ethylenes affords silyl substituted cyclopentenes in high yield.Subsequent reaction of these products with varied electrophiles forms the basis of a new and versatile five-ring annulation sequence.

Full text of DOI:10.1016/S0040-4039(00)86804-5

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