DISCRETE INTRODUCTION OF THE ELECTROPHILE AND NUCLEOPHILE IN AdE-REACTIONS OF DICOBALT HEXACARBONYL COMPLEXES OF CONJUGATED ENYNES.

DOI: 10.1016/S0040-4039(00)85617-8

Source and publish data:

Tetrahedron Letters p. 4419 - 4422 (1982)

Update date:2022-08-03

Topics:

Authors:

Schegolev, A. A.

Smit, W. A.

Kalyan, Y. B.

Krimer, M. Z.

Caple, R.

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Article abstract of DOI:10.1016/S0040-4039(00)85617-8

The dicobalt hexacarbonyl complex of enyne isopropenylacetylene (1) is effective in permitting stepwise Ad_E reactions to the double bond of 1 via stabilization of the intermediate carbenium ion.

Full text of DOI:10.1016/S0040-4039(00)85617-8

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