Synthesis of the first 30-electron triple-decker complexes of the iron group metals with cyclopentadienyl ligands. X-Ray structure of PF6

DOI: 10.1016/0022-328X(87)87168-1

Source and publish data:

Journal of Organometallic Chemistry p. 187 - 198 (1987)

Update date:2022-08-17

Topics:

Authors:

Kudinov, A.R.

Rybinskaya, M.I.

Struchkov, Yu.T.

Yanovskii, A.I.

Petrovskii, P.V.

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Article abstract of DOI:10.1016/0022-328X(87)87168-1

The first 30-electron triple-decker complexes of the iron group metals <(η-C5R5)M(μ,η-C5Me5)M'(η-C5Me5)>PF6 were synthesized by reaction of PF6 or PF6 (R=H, Me) with decamethylmetallocenes M'(η-C5Me5)2 (M'=Fe, Ru, Os

Full text of DOI:10.1016/0022-328X(87)87168-1

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