Helvetica Chimica Acta p. 627 - 632 (1983)
Update date:2022-08-16
Topics:
Manzardo, Giuseppe G.G.
Karpf, Martin
Dreiding, Andre S.
A synthesis of the racemic form of the natural tricyclic hydrocarbon albene (1) from the Diels-Alder adduct 2 of tiglyl chloride and cyclopentadiene is described (24percent yield).The key step 5 -> 6 involves a thermal α-alkynone cyclization (Scheme 3), w
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(1978)