Selective imidoylnitrenes

DOI: 10.1016/S0040-4039(00)71457-2

Source and publish data:

Tetrahedron Letters p. 727 - 730 (1980)

Update date:2022-08-29

Topics:

Authors:

Lwowski, Walter

Rao, O.Subba

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Article abstract of DOI:10.1016/S0040-4039(00)71457-2

Two new imidoylnitrenes and alkoxycarbonylnitrene form a sequence of reactivities : Only ROCON attacks CH bonds, it and ROC(NCN)N convert benzene to azepines. Benzene is not attacked by ROC(NSO₂CH₃)N, but all three nitrenes react with olefins, alcohols, etc.

Full text of DOI:10.1016/S0040-4039(00)71457-2

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