Journal of Molecular Structure p. 229 - 242 (1987)
Update date:2022-08-11
Topics:
Macdonald, John N.
Owen, Noel L.
Rosolini, M.
Analysis of the vibration and rotation spectra together with NMR and mass spectral data for E-propene-1-thiol has shown that the molecule exists in the gas phase in a conformation with the thiol hydrogen atom in a non-planar, near anti orientation with respect to the double bond.This results is assessed in the light of ab initio predictions indicating the existence of both a syn and gauche rotameric form for the molecule.
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