Journal of the Chemical Society. Chemical communications p. 126 - 127 (1985)
Update date:2022-08-11
Topics:
Baldwin, Jack E.
Najera, Carmen
Yus, Miguel
The successive cyclopalladation-oxidation of E-pinacolone, E-2,2-dimethylcyclohexanone, 2,2,6,6-tetramethylcyclohexanone, and E-lupanone oxime led to the corresponding β-acetoxy derivatives; the second palladation in the case of the acetoxy compounds (2) and (8) takes place in one of the remaining methyl groups, being a regiospecific process, and in the case of the cyclic oximes the palladation occurs in the equatorial methyl group.
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