Acetylide Additions to Enediones. Regioselectivity Based on Stereoelectronic Control

DOI: 10.1021/jo00217a055

Source and publish data:

Journal of Organic Chemistry p. 3241 - 3243 (1985)

Update date:2022-08-16

Topics:

Authors:

Liotta, Dennis

Saindane, Manohar

Sunay, Ustun

Jamison, W. Charles L.

Grossman, Judy

Phillips, Preston

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Article abstract of DOI:10.1021/jo00217a055

Regiospecific addition of acetylide anions to enediones can be achieved without the need of protecting groups.The selectivity of these additions appears to be the result of a preference for these anions to add in an axial fashion.

Full text of DOI:10.1021/jo00217a055

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