SYNTHESIS OF A VERSATILE FUNCTIONALIZED TETRAQUINANE. CONVENIENT ACCESS TO 1,3-BISHOMOPENTAPRISMANEDIONE

DOI: 10.1016/S0040-4039(00)89290-4

Source and publish data:

Tetrahedron Letters p. 4051 - 4054 (1985)

Update date:2022-08-23

Topics:

Authors:

Paquette, Leo A.

Nakamura, Koichi

Fischer, John W.

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Article abstract of DOI:10.1016/S0040-4039(00)89290-4

The tetracyclic diene dione 1 has been synthesized by a short oxidative decarboxylation route starting with the domino Diels-Alder adduct 2.Photocyclization of the bisketal of 1 was used to arrive expediently at 1,3-bishomopentaprismanedione (7).

Full text of DOI:10.1016/S0040-4039(00)89290-4

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