Tetrahedron p. 1035 - 1046 (1986)
Update date:2022-08-16
Topics:
Laurie, David
Lucas, Edward
Nonhebel, Derek C.
Suckling, Colin J.
The course of the oxidation of 2,2-dimethylcyclopropylmethanol and 2,2,3,3-tetramethylcyclopropylmethanol by horse liver alcohol dehydrogenase and NAD+ has been investigated.In neither case were ring opened products detected which, in agreement with previous observations, provides no evidence for the intermediacy of radicals in these reactions.The stability of several substituted cyclopropyl-alkyl radicals has been investigated by e.s.r. spectroscopy and the results are discussed with respect to cyclopropane-containing probes of the mechanism of oxidation of lactate dehydrogenase.
View More
Contact:86+21-56421993
Address:3F,BUILDING 10,NO.2889 JINKE ROAD, SHANGHAI.
Contact:0091-265-2313036
Address:311, ATLANTIS HEIGHTS SARABHAI MAIN ROAD,VADIWADI ,VADODARA
HANGZHOU TOYOND BIOTECH CO., LTD
Contact:+86-571-86965177
Address:No. 189, Fengqi East Road, Hangzhou, China
Xiamen Huasing Chemicals Co.Ltd.
Contact:0086-592-6228397
Address:NO.24, Xinglin North 2nd Road,Jimei district
Contact:+86-574-89075960
Address:#100 Xiang Yun Road, New High tech area, Ningbo, China
Doi:10.3987/com-99-8760
(2000)Doi:10.1021/jacs.0c12042
(2021)Doi:10.1021/jo00828a006
(1970)Doi:10.1039/C1967000758b
(1967)Doi:10.1002/anie.201814388
(2019)Doi:10.1021/op700055e
(2007)
