
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 1520 - 1525 (1980)
Update date:2022-08-11
Topics:
Davidson, Iain M. T.
Ring, Morey A.
The low-pressure pyrolysis of methylsilane in the unimolecular fall-off region proceeds mainly by formation of molecular hydrogen: MeSiH3 <*> MeSiH+H2; however, unimolecular formation of methane also occurs: MeSiH3 <*> SiH2+CH4.Arrhenius parameters for both processes are estimated and some thermochemical deductions made.
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