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Gold(1+) cyanide

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Name

Gold(1+) cyanide

EINECS N/A
CAS No. 506-65-0 Density g/cm3
PSA 23.79000 LogP 0.01428
Solubility Slightly soluble in water. Melting Point ~50°C
Formula CAu N Boiling Point 25.7°Cat760mmHg
Molecular Weight 222.984 Flash Point °C
Transport Information N/A Appearance N/A
Safety Explosive reaction when heated with magnesium. When heated to decomposition it emits toxic fumes of CN and cyanogen. See also CYANIDE and GOLD COMPOUNDS. Risk Codes 26/27/28-32-50/53
Molecular Structure Molecular Structure of 506-65-0 (GOLD(I) CYANIDE) Hazard Symbols T+,N
Synonyms

Aurouscyanide; Gold cyanide; Gold monocyanide; Gold(1+) cyanide

Article Data 10

Gold(1+) cyanide Synthetic route

tris(triphenylphosphinegold)oxonium fluoroborate

7646-69-7

sodium hydride

670-54-2

ethenetetracarbonitrile

A

2P(C6H5)3*Au(1+)*BF4(1-)=(P(C6H5)3)2AuBF4

B

506-65-0

gold(I) cyanide

Conditions
ConditionsYield
In tetrahydrofuran stirring suspn. of all substances in abs. THF for 4 h; ppt. sepn., washing (THF, water and ether) and drying gave AuCN; soln. dild. with petroleum ether and cooled to 0°C; ppt. sepn. and washing with petroleum ether gave Au-complex;A 100%
B 67%

tris(triphenylphosphinegold)oxonium fluoroborate

670-54-2

ethenetetracarbonitrile

A

tricyanomethanidebis(triphenylphosphine)gold

B

506-65-0

gold(I) cyanide

Conditions
ConditionsYield
In tetrahydrofuran addn. of Au-complex to soln. of org. compd., stirring (4 h); ppt. sepn., washing (acetone) and drying gave AuCN; evapn. of combined solns. (dryness) and repptn. from acetone by pentane gave Au-complex;A 80%
B 20%

potassium cyanide

29892-37-3

chloro(dimethylsulfide) gold(I)

506-65-0

gold(I) cyanide

Conditions
ConditionsYield
With sulfuric acid In sulfuric acid; water byproducts: HCN, K2SO4; conc. H2SO4 was added in excess to intermediate complex; elem. anal.;70%

2,4-dihydro-1,3-diphenyl(triphenylphosphinegold)cyclopenta{b}indene

670-54-2

ethenetetracarbonitrile

A

2,4-dihydro-1,3-diphenyl(triphenylphosphinegold)cyclopenta{b}indene-tetracyanoethyleneviolet

B

506-65-0

gold(I) cyanide

Conditions
ConditionsYield
In benzene stirring (4 h), ppt. sepn., washing with benzene; extn. by acetone gave AuCN (powder); acetone soln. evapn. to dryness, solid residue dissoln. in benzene, filktration and diln. with petroleum ether to turbidity; ppt. sepn., washing with pentane and drying gave C6H4CH2C5HPh2AuPPh3*TCE; elem. anal.;A n/a
B 69%

2,4-dihydro-1,3-diphenyl(triphenylphosphinegold)cyclopenta{b}indene

670-54-2

ethenetetracarbonitrile

A

tricyanomethanidebis(triphenylphosphine)gold

B

506-65-0

gold(I) cyanide

Conditions
ConditionsYield
In benzene stirring (4 h); ppt. sepn., washing with benzene, extn. by acetone gave AuCN (powder); acetone soln. evapn. gave (PPh3)2AuC(CN)3; elem. anal.;A 1.7%
B 69%
123528-41-6

tetracyanoethylene*C12H8(C6H5)2

tris(triphenylphosphinegold)oxonium fluoroborate

A

tricyanomethanidebis(triphenylphosphine)gold

B

33836-49-6

1,3-diphenyl-2,8-dihydrocyclopenta[a]indene

C

506-65-0

gold(I) cyanide

Conditions
ConditionsYield
In tetrahydrofuran addn. of Au-complex to soln. of org. compd., stirring (4 h); ppt. sepn., washing (THF) and drying gave AuCN; all solns. evapn. to dryness, residue extn. (benzene), ext. evapn. (dryness) gave C6H4CH2C5H2Ph2, residue extn. (benzene) and repptn. from acetone by hexane gave Au-complex;A 59%
B n/a
C 33%
506-65-0

gold(I) cyanide

6476-36-4

tris(1-methylethyl)phosphine

((CH3)2CH)3PAuCN

Conditions
ConditionsYield
In methanol; water under an inert atmosphere; to a suspn. of AuCN in methanol/water was added a soln. of the phosphine in methanol, stirred for 2 h; decanted, evapd. to dryness, washed with H2O, extd. with methanol; elem. anal.;79%

[RuCp(Tpmd)]

506-65-0

gold(I) cyanide

[RuCp(μ-Tpmd){AuCN}]

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.5h; Inert atmosphere; Schlenk technique; Sealed tube;76%
506-65-0

gold(I) cyanide

534-13-4

N,N-dimethylthiourea

288088-85-7

dicyano-1κ(2)C-bis-(dimethylthiourea)-2κ(2)S-digold(I)(Au-Au)

Conditions
ConditionsYield
In water AuCN added to thione soln., heated to 343 K for 30 min; crystn. on cooling, elem. anal.;73%

tetraphenylphosphonium tetraselenotungstate

506-65-0

gold(I) cyanide

672-66-2

Dimethyl(phenyl)phosphine

P(C6H5)4(1+)*(CH3)2(C6H5)PAu(Se)2WSe2(1-)=[P(C6H5)4][((CH3)2(C6H5)P)Au(Se)2WSe2]

Conditions
ConditionsYield
In acetonitrile N2, Schlenk techniques; W-compd. addn. to Au compd. suspn., org. compd.addn., soln. stirring for 60 min, filtration (sintered glass frit), Et2O layering on filtrate top over 10 d, crystn.; crystals filtration off; elem. anal.;63%

Gold(1+) cyanide Chemical Properties

IUPAC Name: Gold(1+) cyanide
CAS: 506-65-0
The Molecular formula of  Gold(1+) cyanide (CAS NO.506-65-0): CAuN
The Molecular Weight of Gold(1+) cyanide (CAS NO.506-65-0): 222.98
The Molecular Structure of Gold(1+) cyanide (CAS NO.506-65-0):
 
Enthalpy of Vaporization: 27.18 kJ/mol 
Boiling Point: 25.7 °C at 760 mmHg 
Vapour Pressure: 740 mmHg at 25°C 
Density: 7.12 g/cm3
Appearance: yellow powder
Product Categories: inorganics;micro/Nanoelectronics;gold;solution deposition precursors.

Gold(1+) cyanide Consensus Reports

Cyanide and its compounds are on the Community Right-To-Know List.

Gold(1+) cyanide Safety Profile

Explosive reaction when heated with magnesium. When heated to decomposition it emits toxic fumes of CN and cyanogen. See also CYANIDE and GOLD COMPOUNDS.
Safety Information about  Gold(1+) cyanide (CAS NO.506-65-0):
Hazard Codes: 
T+,:   N:
Risk Statements about  Gold(1+) cyanide (CAS NO.506-65-0):
R26/27/28: Very Toxic by inhalation, in contact with skin and if swallowed.
R32: Contact with acids liberates very toxic gas.
R50/53: Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements about  Gold(1+) cyanide (CAS NO.506-65-0):
S7: Keep container tightly closed.
S28: After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer).
S29: Do not empty into drains.
S60: This material and/or its container must be disposed of as hazardous waste.
S61: Avoid release to the environment. Refer to special instructions safety data sheet.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).
RIDADR: 1588
HazardClass: 6.1
PackingGroup: II

Gold(1+) cyanide Specification

  Gold(1+) cyanide with CAS number of 506-65-0 is also known as Goldcyanide(au(cn)) ; Gold(+1)cyanide ; Gold cyanide ; Gold(i) cyanide ; GOLd monocyanide ; Gold (I) cyanide (99.9%-Au) ; GoldIcyanideyellowpowder ; Gold(i) cyanide 88% au .

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