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Holmium(III) chloride

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Name

Holmium(III) chloride

EINECS 233-387-1
CAS No. 10138-62-2 Density 3.7 g/cm3
PSA 0.00000 LogP 2.06850
Solubility Soluble in water Melting Point 718 °C(lit.)
Formula Cl3Ho Boiling Point 1500 °C (decomp)
Molecular Weight 271.289 Flash Point N/A
Transport Information N/A Appearance Off-white powder
Safety 26-37/39 Risk Codes 36/37/38
Molecular Structure Molecular Structure of 10138-62-2 (HOLMIUM CHLORIDE) Hazard Symbols IrritantXi
Synonyms

Holmium trichloride;NSC 177680;Holmium chloride (HoCl3);Trichloroholmium;Holmium(III) chloride;

Article Data 50

Holmium(III) chloride Consensus Reports

Reported in EPA TSCA Inventory.

Holmium(III) chloride Specification

 The Holmium(III) chloride with CAS registry number of 10138-62-2 is also known as Holmium(III) chloride. The IUPAC name is Trichloroholmium. It belongs to product categories of Inorganics; Catalysis and Inorganic Chemistry; Chemical Synthesis; Crystal Grade Inorganics; Holmium Salts; HolmiumMetal and Ceramic Science; Salts. Its EINECS registry number is 233-387-1. In addition, the formula is Cl3Ho and the molecular weight is 271.29. This chemical is a off-white powder that soluble in water and may cause inflammation to the skin or other mucous membranes. Besides, it exhibits the same color-changing behavior seen in holmium oxide.

Physical properties about Holmium(III) chloride are: (1)Enthalpy of Vaporization: 16.15 kJ/mol; (2)Vapour Pressure: 33900 mmHg at 25 °C; (3)Exact Mass: 269.836877; (4)MonoIsotopic Mass: 269.836877; (5)Heavy Atom Count: 4; (6)Complexity: 8; (7)Covalently-Bonded Unit Count: 1.

Preparation of Holmium(III) chloride: it is prepared by heating a mixture of holmium(III) oxide and ammonium chloride at 200-250 °C. Equation is as follows:

Ho2O3 + 6 NH4Cl → 2 HoCl3 + 6 NH3 + 2 H2O

When you are using this chemical, please be cautious about it. As a chemical, it is irritating to eyes, respiratory system and skin. During using it, wear suitable gloves and eye/face protection. If contact with eyes accidently, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
1. Canonical SMILES: Cl[Ho](Cl)Cl
2. InChI: InChI=1S/3ClH.Ho/h3*1H;/q;;;+3/p-3
3. InChIKey: PYOOBRULIYNHJR-UHFFFAOYSA-K

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 312mg/kg (312mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: FOOD INTAKE (ANIMAL)

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
Archives of Environmental Health. Vol. 5, Pg. 437, 1962.
mouse LD50 oral 5165mg/kg (5165mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.

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