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Hydrazine,(3,4-difluorophenyl)-

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Name

Hydrazine,(3,4-difluorophenyl)-

EINECS 200-258-5
CAS No. 161886-22-2 Density 1.379 g/cm3
PSA 38.05000 LogP 2.02370
Solubility N/A Melting Point N/A
Formula C6H6F2N2 Boiling Point 210.7 °C at 760 mmHg
Molecular Weight 144.124 Flash Point 81.2 °C
Transport Information N/A Appearance N/A
Safety Risk Codes  Xi:Irritant;
Molecular Structure Molecular Structure of 161886-22-2 (3,4-DIFLUOROPHENYLHYDRAZINE) Hazard Symbols IrritantXi
Synonyms

3,4-Difluorophenylhydrazine;

Article Data 9

Hydrazine,(3,4-difluorophenyl)- Synthetic route

3863-11-4

3,4-difluoroaniline

161886-22-2

3,4-difluorophenyl hydrazine

Conditions
ConditionsYield
Stage #1: 3,4-difluoroaniline With hydrogenchloride; sodium nitrite In water at 0℃; for 1.16667h;
Stage #2: With tin(ll) chloride In water at 0℃;
57.5%
Stage #1: 3,4-difluoroaniline With hydrogenchloride In methanol
Stage #2: With sodium nitrite In methanol; water at 0℃; for 0.333333h;
Stage #3: With hydrogenchloride; tin(ll) chloride In methanol; water at 4℃; for 6h; Further stages.;
Stage #1: 3,4-difluoroaniline With hydrogen bromide; sodium nitrite In water at -10 - -5℃; for 1h; Inert atmosphere;
Stage #2: With tin(ll) chloride In water at -10 - -5℃; for 2h; Inert atmosphere;
Stage #1: 3,4-difluoroaniline With hydrogenchloride; sodium nitrite In dichloromethane; water at 0 - 20℃; for 1.5h;
Stage #2: With tin(ll) chloride In dichloromethane; water at 0℃; for 6h;
7772-99-8

stannous chloride

3863-11-4

3,4-difluoroaniline

161886-22-2

3,4-difluorophenyl hydrazine

Conditions
ConditionsYield
With sodium nitrite In hydrogenchloride; water57.4%
42059-81-4

3-formyl-6-methylchromone

161886-22-2

3,4-difluorophenyl hydrazine

1242460-97-4

C17H12F2N2O2

Conditions
ConditionsYield
With acetic acid In ethanol at 40℃; for 1h;99%
42059-75-6

6,8-dimethyl-3-formylchromone

161886-22-2

3,4-difluorophenyl hydrazine

1242460-93-0

C18H14F2N2O2

Conditions
ConditionsYield
With acetic acid In ethanol at 40℃; for 1h;99%
69155-76-6

6-fluorochromone-3-carboxaldehyde

161886-22-2

3,4-difluorophenyl hydrazine

1242460-92-9

C16H9F3N2O2

Conditions
ConditionsYield
With acetic acid In ethanol at 40℃; for 1h;99%
40682-97-1

7-methyl-4-oxo-(4H)-1-benzopyran-3-carbaldehyde

161886-22-2

3,4-difluorophenyl hydrazine

1242460-95-2

C17H12F2N2O2

Conditions
ConditionsYield
With acetic acid In ethanol at 40℃; for 1h;99%
52817-12-6

6-bromo-4-oxo-4H-chromene-3-carbaldehyde

161886-22-2

3,4-difluorophenyl hydrazine

1242460-96-3

C16H9BrF2N2O2

Conditions
ConditionsYield
With acetic acid In ethanol at 40℃; for 1h;99%
64481-10-3

6,8-dichloro-3-formylchromone

161886-22-2

3,4-difluorophenyl hydrazine

1242460-91-8

C16H8Cl2F2N2O2

Conditions
ConditionsYield
With acetic acid In ethanol at 40℃; for 1h;99%
17422-74-1

3-Formylchromone

161886-22-2

3,4-difluorophenyl hydrazine

1242460-94-1

C16H10F2N2O2

Conditions
ConditionsYield
With acetic acid In ethanol at 40℃; for 1h;99%
42248-31-7

6-Chloro-4-oxo-4H-chromene-3-carbaldehyde

161886-22-2

3,4-difluorophenyl hydrazine

1242460-98-5

C16H9ClF2N2O2

Conditions
ConditionsYield
With acetic acid In ethanol at 40℃; for 1h;99%

Hydrazine,(3,4-difluorophenyl)- Specification

The Hydrazine,(3,4-difluorophenyl)- is an organic compound with the formula C6H6F2N2. The systematic name of this chemical is (3,4-Difluorophenyl)hydrazine. With the CAS registry number 161886-22-2, it is also named as (3,4-Difluoro-phenyl)-hydrazine. The product's categories are Halide; Hydrazine. Besides, its molecular weight is 144.12.

Physical properties about Hydrazine,(3,4-difluorophenyl)- are: (1)ACD/LogP: 2.09; (2)ACD/LogD (pH 5.5): 1.94; (3)ACD/LogD (pH 7.4): 2.09; (4)ACD/BCF (pH 5.5): 16.24; (5)ACD/BCF (pH 7.4): 22.84; (6)ACD/KOC (pH 5.5): 231.95; (7)ACD/KOC (pH 7.4): 326.26; (8)#H bond acceptors: 2; (9)#H bond donors: 3; (10)#Freely Rotating Bonds: 2; (11)Polar Surface Area: 6.48 Å2; (12)Index of Refraction: 1.579; (13)Molar Refractivity: 34.75 cm3; (14)Molar Volume: 104.4 cm3; (15)Polarizability: 13.77×10-24 cm3; (16)Surface Tension: 44.3 dyne/cm; (17)Density: 1.379 g/cm3; (18)Flash Point: 81.2 °C; (19)Enthalpy of Vaporization: 44.69 kJ/mol; (20)Boiling Point: 210.7 °C at 760 mmHg; (21)Vapour Pressure: 0.19 mmHg at 25 °C.

You can still convert the following datas into molecular structure:
(1)InChI: InChI=1/C6H6F2N2/c7-5-2-1-4(10-9)3-6(5)8/h1-3,10H,9H2
(2)InChIKey: KBSCNXDDCDSLLP-UHFFFAOYAO
(3)Std. InChI: InChI=1S/C6H6F2N2/c7-5-2-1-4(10-9)3-6(5)8/h1-3,10H,9H2
(4)Std. InChIKey: KBSCNXDDCDSLLP-UHFFFAOYSA-N

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