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Basic Information
CAS No.: 10025-83-9
Name: Iridium trichloride
Molecular Structure:
Molecular Structure of 10025-83-9 (Iridium trichloride)
Formula: IrCl3
Molecular Weight: 298.579
Synonyms: Iridium (III) chloride;Iridium chloride (IrCl3);
EINECS: 233-044-6
Density: 5,3 g/cm3
Melting Point: 763 °C(lit.)
Solubility: insoluble in water
Appearance: brown powder
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 26-36
PSA: 0.00000
LogP: -8.98800
Synthetic route

iridium

10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With Cl2 In neat (no solvent) in a flow of Cl2 (free from O2, 1 atm) at 500-620°C; at 600-620°C instantaneous reation; at 445 °C only incomplete reaction even after several hours;; sintering at 650°C;100%
With chlorine
With chlorine Irradiation (UV/VIS); reacting with chlorine at 600-620°C by irradn. of sunshine or of magnesium light;

iridium

A

iridium(III) chloride

B

10025-83-9

iridium (III) chloride

C

iridium(I)-chloride

Conditions
ConditionsYield
With chlorine above 600°C, by decompn.;
With Cl2 above 600°C, by decompn.;

iridium

10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
at red heat; product is a mixt. of Ir and IrCl3;
at red heat; product is a mixt. of Ir and IrCl3;

BaO*CO2=BaCO3

3H(1+)*{IrCl4(C2O4)}(3-)*99H2O=H3{IrCl4(C2O4)}*99H2O

A

10025-83-9

iridium (III) chloride

B

516-02-9

barium oxalate

Conditions
ConditionsYield
In water filtering;evapn.;

iridium(III) trichloride hydrate

10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With Cl2 In neat (no solvent) byproducts: H2O; heating IrCl3*H2O in a flow of chlorine at 450-600 °C, reaction starts even at 310 °C;;
at 310°C;

3K(1+)*{IrCl6}(3-)*3H2O=K3{IrCl6}*3H2O

10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With hydrogenchloride In neat (no solvent) at 440°C;
With HCl In neat (no solvent) at 440°C;

3Na(1+)*{IrCl6}(3-)*12H2O=Na3{IrCl6}*12H2O

10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With hydrogenchloride In neat (no solvent) at 440°C;
With HCl In neat (no solvent) at 440°C;

iridium(IV) oxide dihydrate

10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With chlorine by heating;
With Cl2 by heating;

potassium hexachloroiridate(III)

10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With hydrogenchloride at 440 °C;
With HCl at 440 °C;

silver iridium(III) chloride

10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With hydrogenchloride byproducts: AgCl contg. Ir;
With HCl byproducts: AgCl contg. Ir;
Downstream Products
1072-91-9
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    Iridium trichloride CAS NO.10025-83-9

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Specification

The Iridium chloride is an organic compound with the formula IrCl3. The IUPAC name of this chemical is iridium(3+) trichloride. With the CAS registry number 10025-83-9, it is also named as Iridium trichloride. The product's categories are Inorganics; Iridium Salts; Metal and Ceramic Science; Salts; Crystal Grade Inorganics; IridiumMetal and Ceramic Science.

Physical properties about Iridium chloride are: (1)Enthalpy of Vaporization:  16.15 kJ/mol ; (2)Vapour Pressure:  33900 mmHg at 25°C.

Preparation: this chemical can be prepared by Iridium powder and chlorine mixed with a small amount of carbon monoxide. The reaction time is 15 min with reaction temperature of 600 °C.

When you are using this chemical, please be cautious about it as the following:
This chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable protective clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: Cl[Ir](Cl)Cl
(2)InChI: InChI=1/3ClH.Ir/h3*1H;/q;;;+3/p-3
(3)InChIKey: DANYXEHCMQHDNX-DFZHHIFOAH
(4)Std. InChI: InChI=1S/3ClH.Ir/h3*1H;/q;;;+3/p-3
(5)Std. InChIKey: DANYXEHCMQHDNX-UHFFFAOYSA-K