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Manganese

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Name

Manganese

EINECS 231-105-1
CAS No. 7439-96-5 Density 7.3 g/mL at 25 °C(lit.)
PSA 0.00000 LogP 0.00000
Solubility soluble in water Melting Point 1244 °C(lit.)
Formula Mn Boiling Point 1962 °C(lit.)
Molecular Weight 54.938 Flash Point N/A
Transport Information UN 3264 8/PG 3 Appearance silvery or greyish flakes or chunks
Safety 45-43-26-36-36/37/39-27 Risk Codes 36/38-15-11-34-23/24/25
Molecular Structure Molecular Structure of 7439-96-5 (Manganese) Hazard Symbols FlammableF, IrritantXi, ToxicT
Synonyms

Colloidalmanganese;Cutaval;Ele-Max Manganese;JIS-G 1213;MNE 06PB;Manganese element;Manganese-55;Teprosyn Mn;

Article Data 374

Manganese Synthetic route

benzylpentacarbonylmanganese

7439-96-5

manganese

Conditions
ConditionsYield
byproducts: bibenzyl; flash vacuum pyrolysis at 350°C and 0.1 torr;98%
82360-21-2

potassium 6,6-dimethylcyclohexadienide

manganese(ll) chloride

A

7439-96-5

manganese

B

108969-13-7

(dmCh)2Mn

Conditions
ConditionsYield
In tetrahydrofuran byproducts: KCl, C16H22; to slurry of MnCl2 (1.71 mmol) in THF at -78°C added (dmCh)K (3.42 mmol) from solid addn. funnel over 3 h (alternativly, THF soln. of (dmCh)K added dropwise over 3 h), stirred for 4 h, allowed to warm to 25°C, stirred addnl. for 12 h; THF removed, pentane added, filtered, pentane removed;A n/a
B 15%

manganese(III) oxide

7439-96-5

manganese

Conditions
ConditionsYield
With aluminium
With silicon In neat (no solvent) Electric Arc; redn. with Si in carbon electric arc;;

sodium azide

manganese(ll) chloride

A

7439-96-5

manganese

B

manganese nitride

Conditions
ConditionsYield
byproducts: N2, NaCl; vac., heating in ampoule (300-400°C); cooling, washing (MeOH), drying (vac.), powder XRD, FT IR;

manganese(II) chloride tetrahydrate

7439-96-5

manganese

Conditions
ConditionsYield
With NH4SCN; H3BO3; KCl In water Electrochem. Process; under N2; Mn electrodeposited from soln. of MnCl2*4H2O, H3BO3, KCl, and NH4SCN; pH 5.0, at -2.0 - -0.7 V for 180 min;

manganosite

graphite

7439-96-5

manganese

Conditions
ConditionsYield
In neat (no solvent) byproducts: CO; isothermal react. under Ar, mixing of stoich. amts. of MnO and C, placing in an alumina crucible in a tube furnace, heating to 1350°C for 80 min; effects of gangue components on the reduction is studied; determination by X-ray diffraction and EDAX;

manganese(II) sulfate tetrahydrate

7439-96-5

manganese

Conditions
ConditionsYield
With (NH4)2SO4 In not given Electrochem. Process; electrodeposited at pH 8.0; 20-25°C; 4 A/dm**2; no agitation;

tungsten monocarbide

manganese(II) oxide

A

tungsten carbide

B

7439-96-5

manganese

Conditions
ConditionsYield
byproducts: CO; at 1400-1550°C;

manganese(II) oxide

7439-96-5

manganese

Conditions
ConditionsYield
With sodium In neat (no solvent) redn. with Na at 25 °C;;
With aluminium In neat (no solvent) heating in a vessel (coated with CaO or MgO) in presence of cryolite or CaF2;;
With beryllium byproducts: BeO; redn. with Be at 25-1280 °C;;

manganese(II) oxide

7429-90-5

aluminium

A

1333-84-2, 1344-28-1

aluminum oxide

B

7439-96-5

manganese

Conditions
ConditionsYield
Kinetics; byproducts: Al2O3; at 1800°K;

Manganese Consensus Reports

 Manganese and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

Manganese Standards and Recommendations

OSHA PEL: Fume: TWA 1 mg/m3; STEL 3 mg/m3; Compounds: CL 5 mg/m3
ACGIH TLV: Fume: 1 mg/m3; STEL 3 mg/m3; Dust and Compounds: TWA 5 mg/m3; (Proposed: TWA 0.2 mg/m3)
DFG MAK: 0.5 mg/m3

Manganese Analytical Methods

For occupational chemical analysis use OSHA: #ID-125G or NIOSH: Elements (ICP), 7300.

Manganese Specification

The Manganese is an organic compound with the formula Mn. With the CAS registry number 7439-96-5, the IUPAC name of this chemical is manganese. The product's categories are Inorganics; AAS; AAS CRMsAlphabetic; AASSpectroscopy; Application CRMs; M; MA - MDSpectroscopy; Matrix Selection; Nitrate; Spectroscopy; ICP CRMsAlphabetic; ICP-OES/-MS; ICPSpectroscopy; Manganese; Metal and Ceramic Science; Metals; AA Standard SolutionsAlphabetic; NitrateSpectroscopy; Reference/Calibration Standards; Single Solution; Standard Solutions; Catalysis and Inorganic Chemistry; Chemical Synthesis; ManganeseMetal and Ceramic Science. Besides, it should be stored in a cool dry and well-ventilated place.

Preparation: this chemical can be prepared by Manganese carbonate and sulfuric acid.


Uses of Manganese: it is a metal with important industrial metal alloy uses, particularly in stainless steels. Manganese(II) ions function as cofactors for a number of enzymes in higher organisms, where they are essential in detoxification of superoxide free radicals. The element is a required trace mineral for all known living organisms. In larger amounts, and apparently with far greater activity by inhalation, manganese can cause a poisoning syndrome in mammals, with neurological damage which is sometimes irreversible.

When you are using this chemical, please be cautious about it as the following:
It is highly flammable and toxic by inhalation, in contact with skin and if swallowed. Please take off immediately all contaminated clothing. It contacts with water liberates extremely flammable gases and can cause burns. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical is irritating to to eyes and skin. When you are using it, wear suitable gloves and eye/face protection. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: [Mn]
(2)InChI: InChI=1/Mn
(3)InChIKey: PWHULOQIROXLJO-UHFFFAOYAG
(4)Std. InChI: InChI=1S/Mn
(5)Std. InChIKey: PWHULOQIROXLJO-UHFFFAOYSA-N

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
man TCLo inhalation 2300ug/m3 (2.3mg/m3) BRAIN AND COVERINGS: OTHER DEGENERATIVE CHANGES

BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)

BEHAVIORAL: MUSCLE WEAKNESS
American Industrial Hygiene Association Journal. Vol. 27, Pg. 454, 1966.
rat LD50 oral 9gm/kg (9000mg/kg)   "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972Vol. -, Pg. 21, 1972.

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