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Cas Database |
| Name |
N,N-Diglycidyl-4-Glycidyloxyaniline |
EINECS | 225-716-2 |
| CAS No. | 5026-74-4 | Density | 1.306 g/cm3 |
| PSA | 50.06000 | LogP | 1.06820 |
| Solubility | 3.34g/L at 20℃ | Melting Point |
N/A |
| Formula | C15H19NO4 | Boiling Point | 461.606 °C at 760 mmHg |
| Molecular Weight | 277.32 | Flash Point | 144.885 °C |
| Transport Information | N/A | Appearance | N/A |
| Safety | 23-26-36 | Risk Codes | 22-36/37/38-40-43 |
| Molecular Structure |
|
Hazard Symbols |
 Xn
|
| Synonyms |
N-(4-(Oxiranylmethoxy)phenyl)-N-(oxiranylmethyl)oxiranemethanamine;Oxiranemethanamine, N-(4-(oxiranylmethoxy)phenyl)-N-(oxiranylmethyl)-;4-((Oxiran-2-yl)methoxy)-N,N-bis((oxiran-2-yl)methyl)benzenamine; |
Article Data | 1 |
N,N-Diglycidyl-4-Glycidyloxyaniline Synthetic route
| Conditions | Yield |
|---|---|
| Stage #1: 4-amino-phenol; epichlorohydrin In water at 40℃; for 5h; Inert atmosphere; Green chemistry; Stage #2: With sodium hydroxide In water at 55℃; under 135.014 Torr; Solvent; Temperature; Pressure; Green chemistry; | 95% |
| Conditions | Yield |
|---|---|
| In methanol at 20℃; for 48h; | 92% |
- 5026-74-4
p-(diglycidylamino)phenyl glycidyl ether
| Conditions | Yield |
|---|---|
| In 2-methyl-propan-1-ol for 4h; |
- 5026-74-4
p-(diglycidylamino)phenyl glycidyl ether
| Conditions | Yield |
|---|---|
| In 2-methyl-propan-1-ol for 6h; |
- 5026-74-4
p-(diglycidylamino)phenyl glycidyl ether
| Conditions | Yield |
|---|---|
| In 2-methyl-propan-1-ol for 8h; |
- 5026-74-4
p-(diglycidylamino)phenyl glycidyl ether
| Conditions | Yield |
|---|---|
| In 2-methyl-propan-1-ol for 10h; |
- 5026-74-4
p-(diglycidylamino)phenyl glycidyl ether
- polymer, cross-linked, poly(β-vinyloxyethylamine) to N,N-di(2,3-epoxypropyl)-4-(2,3-epoxypropyloxy)aniline feed ratio 1:1; monomer(s): β-vinyloxyethylamine; N,N-di(2,3-epoxypropyl)-4-(2,3-epoxypropyloxy)aniline
polymer, cross-linked, poly(β-vinyloxyethylamine) to N,N-di(2,3-epoxypropyl)-4-(2,3-epoxypropyloxy)aniline feed ratio 1:1; monomer(s): β-vinyloxyethylamine; N,N-di(2,3-epoxypropyl)-4-(2,3-epoxypropyloxy)aniline
| Conditions | Yield |
|---|---|
| In 2-methyl-propan-1-ol Heating; |
- 5026-74-4
p-(diglycidylamino)phenyl glycidyl ether
- polymer, cross-linked, poly(β-vinyloxyethylamine) to N,N-di(2,3-epoxypropyl)-4-(2,3-epoxypropyloxy)aniline feed ratio 2:1; monomer(s): β-vinyloxyethylamine; N,N-di(2,3-epoxypropyl)-4-(2,3-epoxypropyloxy)aniline
polymer, cross-linked, poly(β-vinyloxyethylamine) to N,N-di(2,3-epoxypropyl)-4-(2,3-epoxypropyloxy)aniline feed ratio 2:1; monomer(s): β-vinyloxyethylamine; N,N-di(2,3-epoxypropyl)-4-(2,3-epoxypropyloxy)aniline
| Conditions | Yield |
|---|---|
| In 2-methyl-propan-1-ol Heating; |
- 5026-74-4
p-(diglycidylamino)phenyl glycidyl ether
- polymer, cross-linked, poly(β-vinyloxyethylamine) to N,N-di(2,3-epoxypropyl)-4-(2,3-epoxypropyloxy)aniline feed ratio 3:1; monomer(s): β-vinyloxyethylamine; N,N-di(2,3-epoxypropyl)-4-(2,3-epoxypropyloxy)aniline
polymer, cross-linked, poly(β-vinyloxyethylamine) to N,N-di(2,3-epoxypropyl)-4-(2,3-epoxypropyloxy)aniline feed ratio 3:1; monomer(s): β-vinyloxyethylamine; N,N-di(2,3-epoxypropyl)-4-(2,3-epoxypropyloxy)aniline
| Conditions | Yield |
|---|---|
| In 2-methyl-propan-1-ol Heating; |
- 5026-74-4
p-(diglycidylamino)phenyl glycidyl ether
- polymer, cross-linked, poly(β-vinyloxyethylamine) to N,N-di(2,3-epoxypropyl)-4-(2,3-epoxypropyloxy)aniline feed ratio 4:1; monomer(s): β-vinyloxyethylamine; N,N-di(2,3-epoxypropyl)-4-(2,3-epoxypropyloxy)aniline
polymer, cross-linked, poly(β-vinyloxyethylamine) to N,N-di(2,3-epoxypropyl)-4-(2,3-epoxypropyloxy)aniline feed ratio 4:1; monomer(s): β-vinyloxyethylamine; N,N-di(2,3-epoxypropyl)-4-(2,3-epoxypropyloxy)aniline
| Conditions | Yield |
|---|---|
| In 2-methyl-propan-1-ol Heating; |
N,N-Diglycidyl-4-Glycidyloxyaniline Consensus Reports
Reported in EPA TSCA Inventory.
N,N-Diglycidyl-4-Glycidyloxyaniline Specification
The N,N-Diglycidyl-4-Glycidyloxyaniline, with the CAS registry number 5026-74-4, is also known as 4-(2-Oxiranylmethoxy)-N,N-bis(2-oxiranylmethyl)aniline. It belongs to the product categories of Epoxide Monomers; Monomers; Polymer Science. Its EINECS registry number is 225-716-2. This chemical's molecular formula is C15H19NO4 and molecular weight is 277.32. What's more, both its IUPAC name and systematic name are the same which is called 4-(Oxiran-2-ylmethoxy)-N,N-bis(oxiran-2-ylmethyl)aniline. It should be kept in a cold, sealed and dry place.
Physical properties about N,N-Diglycidyl-4-Glycidyloxyaniline are: (1)ACD/LogP: 0.78; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 0.7; (4)ACD/LogD (pH 7.4): 0.78; (5)ACD/BCF (pH 5.5): 1.93; (6)ACD/BCF (pH 7.4): 2.29; (7)ACD/KOC (pH 5.5): 53.11; (8)ACD/KOC (pH 7.4): 62.94; (9)#H bond acceptors: 5; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 8; (12)Polar Surface Area: 50.06 Å2; (13)Index of Refraction: 1.611; (14)Molar Refractivity: 73.76 cm3; (15)Molar Volume: 212.3 cm3; (16)Surface Tension: 62.5 dyne/cm; (17)Density: 1.305 g/cm3; (18)Flash Point: 144.9 °C; (19)Enthalpy of Vaporization: 72.25 kJ/mol; (20)Boiling Point: 461.6 °C at 760 mmHg; (21)Vapour Pressure: 1.06E-08 mmHg at 25 °C.
When you are dealing with this chemical, you should be very careful. This chemical is inflammation to the skin, eyes and respiratory systemmay. What's more, it may cause sensitisation by skin contacting and it is harmful if swallowed. Therefore, you should wear suitable protective clothing. You can not breathe the gas/fumes/vapour/spray. In case of contacting with eyes, you should rinse immediately with plenty of water. And if you feel unwell seek medical advice immediately.
You can still convert the following datas into molecular structure:
(1) SMILES: O(c3ccc(N(CC1OC1)CC2OC2)cc3)CC4OC4
(2) InChI: InChI=1S/C15H19NO4/c1-3-12(17-9-15-10-20-15)4-2-11(1)16(5-13-7-18-13)6-14-8-19-14/h1-4,13-15H,5-10H2
(3) InChIKey: AHIPJALLQVEEQF-UHFFFAOYSA-N
The toxicity data is as follows:
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| hamster | LD50 | oral | 2739mg/kg (2739mg/kg) | United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. Vol. 8EHQ-1281-0426, |
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