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106-89-8

Basic Information
CAS No.: 106-89-8
Name: Epichlorohydrin
Molecular Structure:
Molecular Structure of 106-89-8 (Epichlorohydrin)
Formula: C3H5ClO
Molecular Weight: 92.53
Synonyms: Oxirane,(chloromethyl)- (9CI);Propane, 1-chloro-2,3-epoxy- (6CI,8CI);(Chloromethyl)ethylene oxide;(Chloromethyl)oxirane;(RS)-Epichlorhydrin;1,2-Epoxy-3-chloropropane;1-Chloro-2,3-epoxypropane;2,3-Epoxypropyl chloride;2-(Chloromethyl)oxirane;3-Chloro-1,2-epoxypropane;3-Chloro-1,2-propylene oxide;3-Chloropropene-1,2-oxide;3-Chloropropylene oxide;Chloropropylene oxide;Glycerol epichlorohydrin;Glycidyl chloride;J 006;NSC 6747;dl-a-Epichlorohydrin;a-Epichlorohydrin;g-Chloropropylene oxide;
EINECS: 203-439-8
Density: 1.205 g/cm3
Melting Point: -57 °C
Boiling Point: 116.1 °C at 760 mmHg
Flash Point: 33.9 °C
Solubility: 6 g/100 mL (10 °C) in water
Appearance: clear, colorless
Hazard Symbols: ToxicT
Risk Codes: 45-10-23/24/25-34-43
Safety: 53-45
Transport Information: UN 2023 6.1/PG 2
PSA: 12.53000
LogP: 0.62400
Synthetic route
107-05-1

3-chloroprop-1-ene

106-89-8

epichlorohydrin

Conditions
ConditionsYield
With Cumene hydroperoxide at 60 - 120℃; under 7500.75 Torr; Temperature; Pressure;99%
With Cumene hydroperoxide at 60 - 120℃; under 7500.75 Torr; Temperature; Pressure;98%
With 1-phenylethyl hydroperoxide In ethylbenzene at 30 - 50℃; under 750.075 Torr; Pressure; Temperature; Reagent/catalyst;98%
96-23-1

1,3-Dichloro-2-propanol

106-89-8

epichlorohydrin

Conditions
ConditionsYield
With resin IRA-440 In dichloromethane for 24h; Ambient temperature;98%
With strong basic ion-exchange resin IRA 440 In dichloromethane for 24h; Product distribution; Ambient temperature; other basic ion-exchange resins; other glycerol dihalohydrins; other solvents and time;98%
With calcium hydroxide inactive form;
35952-61-5

(C4H9)3SnOCH(CH2Cl)2

A

1461-22-9

tributyltin chloride

B

78-95-5

chloroacetone

C

106-89-8

epichlorohydrin

Conditions
ConditionsYield
63% decompn. at 210°C (1 h);A n/a
B 5%
C 95%
83682-72-8

γ,γ-dichloropropanol

106-89-8

epichlorohydrin

Conditions
ConditionsYield
With sodium hydroxide at 20℃; Temperature;94.1%
107-05-1

3-chloroprop-1-ene

A

4151-97-7

1-chloro-3-methoxypropan-2-ol

B

96-24-2

3-monochloro-1,2-propanediol

C

106-89-8

epichlorohydrin

Conditions
ConditionsYield
With dihydrogen peroxide; TS-1 In methanol; water; 1,2-dichloro-benzene at 25 - 40℃; for 1h; Product distribution / selectivity;A n/a
B n/a
C 94%
616-23-9

2,3-Dichloro-1-propanol

106-89-8

epichlorohydrin

Conditions
ConditionsYield
With water; sodium hydroxide at 50℃; for 0.00833333h; Time; Temperature; Concentration;92.4%
With potassium hydroxide
556-52-5

oxiranyl-methanol

106-89-8

epichlorohydrin

Conditions
ConditionsYield
With 1-chloro-1-(dimethylamino)-2-methyl-1-propene In dichloromethane at 0 - 20℃; Inert atmosphere;85%
96-23-1

1,3-Dichloro-2-propanol

A

78-95-5

chloroacetone

B

106-89-8

epichlorohydrin

Conditions
ConditionsYield
With HT4-c823 In water at 149.84℃; under 750.075 Torr; for 0.5h; Catalytic behavior; Reagent/catalyst; Temperature; Flow reactor; chemoselective reaction;A 18.9%
B 80.5%
102129-99-7

(R,S)-2-hydroxy-3-chloropropyl p-toluenesulfonate

106-89-8

epichlorohydrin

Conditions
ConditionsYield
With sodium ethane-1,2-diolate In ethylene glycol at 20℃; for 0.25h;79%
589-96-8

(+/-)-1-Acetoxy-2,3-dichloropropane

106-89-8

epichlorohydrin

Conditions
ConditionsYield
With calcium hydroxide 1.) H2O, r.t., 1 h, 2.) hexane, 6 h;77%
56-81-5

glycerol

106-89-8

epichlorohydrin

Conditions
ConditionsYield
Stage #1: glycerol With hydrogenchloride; Adipic acid In water at 120℃; for 8h;
Stage #2: With calcium hydroxide
67.5%
With phosphorus trichloride
With hydrogenchloride anschl. mit Aetzkali;
4540-44-7

1-bromo-3-chloro-propan-2-ol

106-89-8

epichlorohydrin

Conditions
ConditionsYield
With sodium ethane-1,2-diolate In ethylene glycol at 20℃; for 0.25h;58%
With potassium hydroxide levorotatory form;
616-23-9

2,3-Dichloro-1-propanol

A

57090-45-6

(2R)-3-chloro-1,2-propanediol

B

60827-45-4

(S)-3-chloropropan-1,2-diol

C

(S)-1,3-dichloro-1-propanol

D

106-89-8

epichlorohydrin

Conditions
ConditionsYield
With epoxide hydrolase from Agrobacterium radiobacter AD1; halohydrin dehalogenase from Agrobacterium radiobacter AD1; Tris-SO4 buffer In water at 30℃; for 20h; pH=7.5; kinetic resolution; Further byproducts given;A n/a
B n/a
C 49.5%
D n/a
7722-84-1

dihydrogen peroxide

107-05-1

3-chloroprop-1-ene

A

7732-18-5

water

B

106-89-8

epichlorohydrin

Conditions
ConditionsYield
With titanium-containing zeolite In methanol at 35℃; Mechanism; Solvent;A n/a
B 29.8%
107-05-1

3-chloroprop-1-ene

A

100-52-7

benzaldehyde

B

106-89-8

epichlorohydrin

Conditions
ConditionsYield
With molybdenum blue; dihydrogen peroxide; bis(tri-n-butyltin)oxide In chloroform at 25℃; for 10h;A 1%
B 48 % Turnov.
96-23-1

1,3-Dichloro-2-propanol

A

56-81-5

glycerol

B

106-89-8

epichlorohydrin

Conditions
ConditionsYield
With potassium hydroxide
3674-10-0

1,3-dichloro-2-acetoxypropane

A

75-36-5

acetyl chloride

B

106-89-8

epichlorohydrin

Conditions
ConditionsYield
beim Stehenlassen;
79-21-0

peracetic acid

107-05-1

3-chloroprop-1-ene

106-89-8

epichlorohydrin

Conditions
ConditionsYield
With catalysts
(+-)-2,3-dichloro-propan-1-ol

(+-)-2,3-dichloro-propan-1-ol

106-89-8

epichlorohydrin

Conditions
ConditionsYield
With calcium hydroxide
With sodium hydroxide Herstellung eines mit Chlor-36 markierten Praeparats;
4540-44-7

1-bromo-3-chloro-propan-2-ol

potash

potash

A

10035-10-6, 12258-64-9

hydrogen bromide

B

106-89-8

epichlorohydrin

96-23-1

1,3-Dichloro-2-propanol

KOH

KOH

106-89-8

epichlorohydrin

616-23-9

2,3-Dichloro-1-propanol

potash

potash

106-89-8

epichlorohydrin

616-23-9

2,3-Dichloro-1-propanol

sodium hydroxide

sodium hydroxide

106-89-8

epichlorohydrin

Conditions
ConditionsYield
at 0℃;
at 0℃; Geschwindigkeit;
at 25℃; Geschwindigkeit;
26484-95-7

1-chloro-3-iodopropan-2-ol

KOH-solution

KOH-solution

A

10034-85-2

hydrogen iodide

B

106-89-8

epichlorohydrin

60-29-7

diethyl ether

96-23-1

1,3-Dichloro-2-propanol

sodium amalgam

sodium amalgam

A

107-18-6

allyl alcohol

B

106-89-8

epichlorohydrin

60-29-7

diethyl ether

96-23-1

1,3-Dichloro-2-propanol

sodium

sodium

A

187737-37-7

propene

B

107-18-6

allyl alcohol

C

106-89-8

epichlorohydrin

64-17-5

ethanol

96-23-1

1,3-Dichloro-2-propanol

powdered NaOH

powdered NaOH

A

4043-59-8

1,3-diethoxy-isopropanol

B

106-89-8

epichlorohydrin

C

glycidethyl ether

glycidethyl ether

3-hydroxy-benzoic acid-(2-chloro-1-chloromethyl-ethyl ester)

potash

potash

106-89-8

epichlorohydrin

Conditions
ConditionsYield
at 100℃;
110-91-8

morpholine

106-89-8

epichlorohydrin

40893-69-4

1-chloro-3-(4-morpholinyl)-2-propanol

Conditions
ConditionsYield
In ethanol for 24h; Heating;100%
With zinc(II) chloride In water at 60℃; for 8h; regioselective reaction;96%
In water at 0 - 5℃; for 4h;92%
120-47-8

Ethyl 4-hydroxybenzoate

106-89-8

epichlorohydrin

50625-94-0

ethyl 4-(glycidyloxy)benzoate

Conditions
ConditionsYield
With sodium carbonate; N,N-dimethyl-formamide at 80℃; for 12h; Inert atmosphere;100%
With potassium carbonate In acetone for 20h; Heating;
With potassium carbonate In butanone Heating;
With potassium carbonate In acetone; toluene13.5 gm (61%)
With sodium hydroxide
64-19-7

acetic acid

106-89-8

epichlorohydrin

24573-30-6

3-chloro-2-hydroxy-1-propyl acetate

Conditions
ConditionsYield
With iron(III) chloride at 20 - 70℃; for 24.1667h;100%
With tin(IV)tetraphenylporphyrinato trifluoromethanesulfonate for 0.666667h; Heating;99%
With cerium(IV) triflate at 80℃; for 0.0833333h;93%
106-89-8

epichlorohydrin

108-95-2

phenol

122-60-1

Phenyl glycidyl ether

Conditions
ConditionsYield
Stage #1: phenol With sodium hydroxide In water at 25℃; for 0.666667h;
Stage #2: epichlorohydrin In water at 30 - 35℃; for 16h;
100%
With n-Bu4NOSO2OCH2CHOHCH3; potassium carbonate at 75 - 80℃; for 1.5h;91%
With n-BuNOSO2OCH2CHOHCH3; potassium carbonate at 75 - 80℃; for 1.5h; other aryl alcohols, var. phase transfer catalysts, var. reaction time;91%
106-89-8

epichlorohydrin

4540-44-7

1-bromo-3-chloro-propan-2-ol

Conditions
ConditionsYield
With hydrogen bromide at -60℃; for 16h;100%
With dimethylbromosulphonium bromide In acetonitrile at 20℃; for 0.333333h;98%
With ammonium cerium(IV) nitrate; tetrabutylammomium bromide In tert-butyl alcohol for 1.5h; Ambient temperature;96%
106-89-8

epichlorohydrin

96-23-1

1,3-Dichloro-2-propanol

Conditions
ConditionsYield
With hydrogenchloride In dichloromethane for 12h; Ambient temperature;100%
With hydrogenchloride In water100%
With chloro-trimethyl-silane; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate at 20℃; for 1h; ring opening reaction;99%
106-89-8

epichlorohydrin

19030-86-5

bis(3-chloro-2-hydroxypropyl)sulfide

Conditions
ConditionsYield
With hydrogenchloride; sodium hydrogen sulfide monohydrate; sodium hydroxide In methanol; water at 6℃;100%
With hydrogen sulfide; tetrabutylammomium bromide In toluene at 20 - 25℃; Solvent; Temperature; Reagent/catalyst;96%
With hydrogen sulfide
108-18-9

diisopropylamine

106-89-8

epichlorohydrin

55211-97-7

1-Chlor-2-hydroxy-3-diisopropylamino-methyl-propan

Conditions
ConditionsYield
In ethanol for 24h; Heating;100%
In water
62-53-3

aniline

106-89-8

epichlorohydrin

76226-32-9, 15949-12-9

N-(3-chloro-2-hydroxypropyl)aniline

Conditions
ConditionsYield
With lithium bromide at 20℃; for 5h;100%
With Ni2+-metallodendrimer grafted on mesoporous polymethacrylate based Sepabeads EB-EP-400 In neat (no solvent) at 20℃; for 0.5h; Reagent/catalyst; Solvent; Green chemistry; regioselective reaction;97%
With BiCl6(3-)*2C4H10N2*ClH*3H(1+)*H2O at 20℃; for 0.116667h; Neat (no solvent); regioselective reaction;96%
123-75-1

pyrrolidine

106-89-8

epichlorohydrin

58759-70-9

1-chloro-3-(1-pyrrolidinyl)-2-propanol

Conditions
ConditionsYield
In ethanol for 24h; Heating;100%
In ethanol at 20℃; under 2585.81 Torr; for 0.0166667h; microwave irradiation;65%
109-83-1

(2-hydroxyethyl)(methyl)amine

106-89-8

epichlorohydrin

63125-83-7

1-Chlor-2-hydroxy-3-(N-methyl-N-2-hydroxyethyl)-amino-propan

Conditions
ConditionsYield
at 40 - 70℃;100%
In water at 13 - 34℃; for 1.41667h;
In isopropyl alcohol
2380-94-1

1H-indol-4-ol

106-89-8

epichlorohydrin

35308-87-3

4-(oxiranylmethoxy)-1H-indole

Conditions
ConditionsYield
With potassium hydroxide In dimethyl sulfoxide at 45℃; for 4h;100%
Stage #1: 1H-indol-4-ol; epichlorohydrin With potassium hydroxide In dimethyl sulfoxide at 45℃; for 4h;
Stage #2: With ammonium chloride In water
99%
With potassium hydroxide In dimethyl sulfoxide at 45℃; for 4h;99%
5373-72-8

4-phenyl-Δ2-1,2,4-triazoline-5-thione

106-89-8

epichlorohydrin

134619-57-1

4-phenyl-3-(1-chloro-2-hydroxypropylthio)-1,2,4-triazole

Conditions
ConditionsYield
In ethanol at 20℃; for 5h;100%
112-92-5

1-octadecanol

106-89-8

epichlorohydrin

16245-97-9

octadecyl glycidyl ether

Conditions
ConditionsYield
With sodium hydroxide; Aliquat 336 In cyclohexane Heating;100%
With sodium hydroxide; Aliquat 336 In cyclohexane Heating;99%
With sodium hydroxide; Aliquat 336 In cyclohexane for 4h; Heating;99%
7677-24-9

trimethylsilyl cyanide

106-89-8

epichlorohydrin

81091-27-2

4-chloro-3-trimethylsiloxybutyronitrile

Conditions
ConditionsYield
With erbium(III) triflate at 0 - 20℃; for 0.166667h; regioselective reaction;100%
ytterbium cyanide In tetrahydrofuran at 25℃; for 0.3h;91%
124-38-9

carbon dioxide

106-89-8

epichlorohydrin

2463-45-8

4-chloromethyl-[1,3]dioxolan-2-one

Conditions
ConditionsYield
With dmap; CrTTPCl at 60℃; under 37751.8 - 40337.5 Torr; for 18h;100%
With triphenylphosphine; phenol at 120℃; under 30002.4 Torr; for 14h;100%
With triethylamine; binaphthyldiamino Zn(II) salen-type compex In dichloromethane at 100℃; under 25858.1 Torr;100%
1502-03-0

Cyclododecylamine

106-89-8

epichlorohydrin

1-Chloro-3-cyclododecylamino-propan-2-ol

Conditions
ConditionsYield
In ethanol for 24h; Heating;100%
16966-40-8

isoselenocyanatotrimethylsilane

106-89-8

epichlorohydrin

128256-05-3

3-Chloro-2-trimethylsiloxypropyl selenocyanate

Conditions
ConditionsYield
potassium selenocyanate In hexane at 40℃; for 24h;100%
5452-37-9

cyclooctylamine

106-89-8

epichlorohydrin

1-Chloro-3-cyclooctylamino-propan-2-ol

Conditions
ConditionsYield
In ethanol for 24h; Heating;100%
15598-34-2

pyridinium perchlorate

106-89-8

epichlorohydrin

1-(2-hydroxy-3-chloropropyl)pyridinium perchlorate

Conditions
ConditionsYield
With pyridine In ethanol for 3h; Product distribution; Heating; further cycloimmonium salts;100%
With pyridine In ethanol for 3h; Heating;100%
52827-74-4

4-methylpyridinium perchlorate

106-89-8

epichlorohydrin

1-(2-hydroxy-3-chloropropyl)-4-methylpyridinium perchlorate

Conditions
ConditionsYield
With picoline for 1h; Heating;100%
102-92-1

cinnamoyl chloride

106-89-8

epichlorohydrin

157140-94-8

1,3-dichloro-2-propyl cinnamate

Conditions
ConditionsYield
With yttrium(III) chloride In dichloromethane for 36h; Ambient temperature;100%
85095-40-5

N-(1-chlorohexafluoro-1-methylethyl)benzenesulfinimidoyl chloride

106-89-8

epichlorohydrin

91363-16-5

C12H10Cl3F6NOS

Conditions
ConditionsYield
In tetrachloromethane at 25℃; for 48h;100%
85095-41-6

N-(2-chlorohexafluoroisopropyl)-p-toluenesulfinimidoyl chloride

106-89-8

epichlorohydrin

91363-17-6

C13H12Cl3F6NOS

Conditions
ConditionsYield
In tetrachloromethane at 25℃; for 48h;100%
101-83-7

N-cyclohexyl-cyclohexanamine

106-89-8

epichlorohydrin

150389-77-8

1-Chloro-3-dicyclohexylamino-propan-2-ol

Conditions
ConditionsYield
In ethanol for 24h; Heating;100%
151073-99-3

(2-trimethylsilylprop-2-en-1-yl)tributylstannane

106-89-8

epichlorohydrin

1-Chloro-5-(trimethylsilyl)-5-hexen-2-ol

Conditions
ConditionsYield
With ethylaluminum dichloride In dichloromethane at -78℃; for 19h;100%
1745-81-9

2-Allylphenol

106-89-8

epichlorohydrin

49716-04-3

1-(2-allyl-phenoxy)-3-chloro-propan-2-ol

Conditions
ConditionsYield
With pyridine In chloroform; water; phenol100%
With piperidine Heating;
106-89-8

epichlorohydrin

1131-60-8

p-cyclohexylphenol

67006-99-9

2-[(4-cyclohexylphenoxy)methyl]oxirane

Conditions
ConditionsYield
With sodium hydroxide for 1h; Reflux;100%
With sodium In isopropyl alcohol 1.) 10 min., reflux, 2.) 16 h., room temp.;
106-89-8

epichlorohydrin

36636-44-9

bis(2-bromo-2-chloropropyl)(2-bromo-3-chloropropyl)phosphonate

Conditions
ConditionsYield
With phosphorus tribromide at 0 - 40℃;100%
106-89-8

epichlorohydrin

108-95-2

phenol

140630-45-1

(R)-1-chloro-3-phenoxy-2-propanol

Conditions
ConditionsYield
With chiral oligo-(salen)Co(OTs) complexes; lutidinium p-toluene sulfonate In acetonitrile at 4℃; for 4h;100%
With (R,R)-(salen)Co(H2O); 3 A molecular sieve In various solvent(s) at -15℃;97%
With C57H68N4O8(2-)*Co(3+)*C7H7O3S(1-); C56H66N2O6(2-)*Co(3+)*C7H7O3S(1-) In tetrachloromethane at 4 - 20℃; for 6h; stereoselective reaction;95%
With Co(salen) macrocycles 1(OTs) In tert-butyl methyl ether at 20℃; for 9h; optical yield given as %ee; enantioselective reaction;91%
With Co(salen) macrocycles 1(OTs) In tert-butyl methyl ether at 20℃; Kinetics; enantioselective reaction;
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    Epichlorohydrin

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    Epichlorohydrin ECH grade

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    Epichlorohydrin

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    Epichlorohydrin,CAS 106-89-8

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Chemistry

Product Name: Epichlorohydrin (CAS NO.106-89-8)

Molecular Formula: C3H5ClO
Molecular Weight: 92.52g/mol
Mol File: 106-89-8.mol
EINECS: 203-439-8
Boiling point: 116.1 °C at 760 mmHg
Storage Temperature: Refrigerator (+4°C) + Flammables area
Flash Point: 33.9 °C
Density: 1.205 g/cm3
Refractive index: n20/D 1.438(lit.)
Stability: Stability Unstable. Flammable - note wide explosion limits and low flash point. Vapours may flow along surfaces to source of ignition. Contact with strong oxidisers may lead to fire. Incompatible with strong acids, strong bases, strong oxidizing agents, metal salts, amines, aluminium, chlorine and a variety of chlorine compounds, most com
Index of Refraction: 1.443 
Molar Refractivity: 20.37 cm3 
Molar Volume: 76.7 cm3 
Surface Tension: 35.6 dyne/cm
Enthalpy of Vaporization: 33.98 kJ/mol
Vapour Pressure: 22 mmHg at 25°C
XLogP3-AA: 0.5
H-Bond Donor: 0
H-Bond Acceptor: 1
Structure Descriptors of Epichlorohydrin (CAS NO.106-89-8):
  IUPAC Name: 2-(chloromethyl)oxirane
  Canonical SMILES: C1C(O1)CCl
  InChI: InChI=1S/C3H5ClO/c4-1-3-2-5-3/h3H,1-2H2 
  InChIKey: BRLQWZUYTZBJKN-UHFFFAOYSA-N
Product Categories: Chlorepoxypropane (Epichlorohydrin); Organics; Oxiranes; Simple 3-Membered Ring Compounds

Uses

 Epichlorohydrin (CAS NO.106-89-8) is a highly reactive compound,it is often used in the production of plastics,glycerol,  and elastomers. Epichlorohydrin is a versatile precursor in the synthesis of many organic compounds. Epichlorohydrin is also used in water purification and paper reinforcement,such as in the food industry to manufacture coffee filters,tea bags,  and sausage/salami casings.

Production

Epichlorohydrin can be manufactured from allyl chloride in two steps:

Toxicity Data With Reference

1.    

skn-rbt 10 mg/24H open

    JIHTAB    Journal of Industrial Hygiene and Toxicology. 30 (1948),63.
2.    

eye-rbt 100 mg/24H MOD

    85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,769.
3.    

dni-hmn:hla 2700 µmol/L

    MUREAV    Mutation Research. 92 (1982),427.
4.    

sce-hmn:lym 10 nmol/L

    CARYAB    Caryologia. 34 (1981),261.
5.    

spm-mus-ihl 5 mg/m3

    MUREAV    Mutation Research. 85 (1981),287.
6.    

orl-mus TDLo:1200 mg/kg (female 6-15D post):TER

    JTEHD6    Journal of Toxicology and Environmental Health. 9 (1982),87.
7.    

ihl-rat TCLo:50 ppm/6H (male 50D pre):REP

    TXAPA9    Toxicology and Applied Pharmacology. 68 (1983),415.
8.    

orl-rat TDLo:60 g/kg/81W-I:CAR

    GANNA2    Gann. Japanese Journal of Cancer Research. 71 (1980),922.
9.    

ihl-rat TCLo:100 ppm/6H/30D-C:CAR

    JJIND8    JNCI, Journal of the National Cancer Institute. 65 (1980),751.
10.    

ipr-mus TDLo:2400 mg/kg/8W-I:NEO

    TXAPA9    Toxicology and Applied Pharmacology. 82 (1986),19.

 

Consensus Reports

NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2A IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 , 1987,p. 202.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 11 , 1976,p. 131.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . EPA Genetic Toxicology Program. Community Right-To-Know List. EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory.

Safety Profile

Confirmed carcinogen with experimental carcinogenic data. Poison by ingestion, skin contact, intravenous, and intraperitoneal routes. Moderately toxic by inhalation. An experimental teratogen. Other experimental reproductive effects. Human systemic effects by inhalation: respiratory, nose, and eyes. Human mutation data reported. A skin and eye irritant. A sensitizer. Flammable liquid when exposed to heat or flame. Explosive reaction with aniline. Reaction with trichloroethylene forms the explosive dichloroacetylene. Ignition on contact with potassium tert-butoxide. Violent reaction with sulfuric acid or isopropylamine. Exothermic polymerization on contact with strong acids, caustic alkalies, aluminum, aluminum chloride, iron(III) chloride, or zinc. When heated to decomposition it emits toxic fumes of Cl.
Hazard Codes : T Toxic
Risk Statements  :45-10-23/24/25-34-43 
R45:May cause cancer. 
R10:Flammable. 
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed. 
R43:May cause sensitization by skin contact.
Safety Statements  :53-45 
S53:Avoid exposure - obtain special instructions before use. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR:  UN 2023 6.1/PG 2
WGK Germany:  3

Standards and Recommendations

OSHA PEL: TWA 2 ppm (skin)
ACGIH TLV: TWA 0.5 ppm (skin); Animal Carcinogen
DFG MAK: DFG TRK: Animal Carcinogen, Suspected Human Carcinogen
NIOSH REL: Minimize exposure
DOT Classification:  6.1; Label: Poison

Analytical Methods

For occupational chemical analysis use NIOSH: Epichlorohydrin, 1010.

Specification

 Epichlorohydrin , its CAS NO. is 106-89-8, the synonyms are 1-Chloro-2,3-epoxy propane ; 2-(Chloromethyl)oxirane ; 3-Chloro-1,2-epoxypropane . 

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