- 22737-37-7Silanamine,1,1,1-trimethyl-N-[(trimethylsilyl)oxy]-
- 22738-98-3Benzaldehyde,3-[(2E,4E)-5-[(1S,2S,3S,6R)-3-(acetyloxy)-1,2,6-trimethyl-5-oxocyclohexyl]-3-methyl-2,4-pentadien-1-yl]-5-chloro-2,4-dihydroxy-6-methyl-
- 2273-93-07H-Purine,2,6-dichloro-7-methyl-
- 2274-11-52-Propenoic acid,1,1'-(1,2-ethanediyl) ester
- 2274-13-72-Propenamide,N,N-dibutyl-
- 22741-52-21,2-Propanediol,3-[(1,1-dimethylethyl)amino]-
- 22743-71-1Peroxide,cyclohexylidenebis[(1,1-dimethylbutyl) (8CI,9CI)
- 22744-12-32-(4-(Methoxycarbonyl)phenyl)acetic acid
- 2274-42-2Acetonitrile,2-(methylsulfonyl)-
- 227456-27-13-Mercapto-2-methylpenta-1-ol
Hot Products
- 104987-11-3Tacrolimus
- 141-53-7Sodium formate
- 8001-54-5Quaternary ammonium compounds, alkylbenzyldimethyl, chlorides
- 9003-39-8Povidone
- 10161-34-9Trenbolone acetate
- 402957-28-2Telaprevir
- 68-19-9Cyanocobalamin
- 7631-86-9Silicon dioxide
- 302-79-4Tretinoin
- 77-92-9Citric acid
|
Basic Information |
|
Post buying leads |
|
Suppliers |
|
Cas Database |
| Name |
O-(Trimethylsilyl)hydroxylamine |
EINECS | N/A | ||||||||||||||||||
| CAS No. | 22737-36-6 | Density | 0.86 | ||||||||||||||||||
| PSA | 35.25000 | LogP | 1.41190 | ||||||||||||||||||
| Solubility | N/A | Melting Point |
N/A |
||||||||||||||||||
| Formula | C3H11 N O Si | Boiling Point | 98-100 °C(lit.) | ||||||||||||||||||
| Molecular Weight | 105.212 | Flash Point | 48 °F | ||||||||||||||||||
| Transport Information | UN 2733 | Appearance | clear colorless liquid | ||||||||||||||||||
| Safety |
|
Risk Codes | R11;R34 | ||||||||||||||||||
| Molecular Structure |
|
Hazard Symbols |
 
|
||||||||||||||||||
| Synonyms |
O-(Trimethylsilyl)hydroxylamine;Trimethylsiloxyamine |
Article Data | 10 |
O-(Trimethylsilyl)hydroxylamine Synthetic route
A
- 107-46-0
Hexamethyldisiloxane
B
- 22737-36-6
O-Trimethylsilylhydroxylamine
C
- 2362-10-9
1,3-Bis(chloromethyl)-1,1,3,3-tetramethyldisiloxane
| Conditions | Yield |
|---|---|
| In water; acetone at 60℃; | A n/a B 91% C n/a |
- 75-77-4
chloro-trimethyl-silane
- 22737-36-6
O-Trimethylsilylhydroxylamine
| Conditions | Yield |
|---|---|
| With hydroxylamine hydrochloride In dichloromethane; ethylenediamine for 24h; | 80% |
| With hydroxylamine hydrochloride; ethylenediamine 1.) CH2Cl2, RT, 6 h, 2.) CH2Cl2, RT, 24 h; Yield given. Multistep reaction; | |
| With pyridine; hydroxylamine hydrochloride at 20℃; |
- 7379-79-5
trimethylsilyl amine
- 22737-36-6
O-Trimethylsilylhydroxylamine
| Conditions | Yield |
|---|---|
| With hydroxylamine hydrochloride In diethyl ether; ammonia |
- 999-97-3
1,1,1,3,3,3-hexamethyl-disilazane
- 22737-36-6
O-Trimethylsilylhydroxylamine
| Conditions | Yield |
|---|---|
| With hydroxylamine hydrochloride; triethylamine In pentane | |
| With tri-n-propylamine; hydroxylamine hydrochloride |
- 999-97-3
1,1,1,3,3,3-hexamethyl-disilazane
A
- 107-46-0
Hexamethyldisiloxane
B
- 22737-36-6
O-Trimethylsilylhydroxylamine
| Conditions | Yield |
|---|---|
| With tri-n-propylamine; hydroxylamine hydrochloride for 24h; Ambient temperature; Yield given; |
- 79-37-8
oxalyl dichloride
- 22737-36-6
O-Trimethylsilylhydroxylamine
| Conditions | Yield |
|---|---|
| In dichloromethane; ethyl acetate | 100% |
| Conditions | Yield |
|---|---|
| With lithium perchlorate In diethyl ether at 20℃; for 0.5h; | 98% |
| Conditions | Yield |
|---|---|
| In pentane at 20℃; for 12h; | 96% |
| Conditions | Yield |
|---|---|
| With lithium perchlorate In diethyl ether at 20℃; for 0.5h; | 96% |
| Conditions | Yield |
|---|---|
| With chloro-trimethyl-silane; lithium perchlorate In diethyl ether at 20℃; for 2h; Friedel-Crafts reaction; | 96% |
O-(Trimethylsilyl)hydroxylamine Chemical Properties
Molecular Structure of O-(Trimethylsilyl)hydroxylamine (CAS NO.22737-36-6):
.gif){kind=small}
Systematic Name: (Aminooxy)(trimethyl)silane
Molecular Formula: C3H11NOSi
Molecular Weight: 105.21
storage temp.: 2-8 °C
Index of Refraction: 1.398
Molar Refractivity: 29.94 cm3
Molar Volume: 123.8 cm3
Surface Tension: 19.2 dyne/cm
Density: 0.849 g/cm3
Flash Point: 8.9 °C
Enthalpy of Vaporization: 33.84 kJ/mol
Boiling Point: 99 °C at 760 mmHg
Vapour Pressure: 39 mmHg at 25 °C
Appearance: clear colorless liquid
SMILES: O(N)[Si](C)(C)C
InChI: InChI=1/C3H11NOSi/c1-6(2,3)5-4/h4H2,1-3H3
InChIKey: AEKHNNJSMVVESS-UHFFFAOYAT
Product Categories: Hydroxylamines; Hydroxylamines (O-Substituted); Si (Classes of Silicon Compounds); Silanols; Si-O Compounds
O-(Trimethylsilyl)hydroxylamine Safety Profile
Safety Information of O-(Trimethylsilyl)hydroxylamine (CAS NO.22737-36-6):
Hazard Codes: 
F,
C
Risk Statements: 11-34
R11:Highly flammable.
R34:Causes burns.
Safety Statements: 16-26-36/37/39-45
S16:Keep away from sources of ignition.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 2733 3/PG 2
WGK Germany: 3
F: 10-21
TSCA: No
HazardClass: 3.1
PackingGroup: II
O-(Trimethylsilyl)hydroxylamine Specification
O-(Trimethylsilyl)hydroxylamine (CAS NO.22737-36-6), its Synonyms are Hydroxylamine,O-(trimethylsilyl)- ; Trimethylsiloxyamine ; Aminoxytrimethylsilane .
What can I do for you?
Get Best Price
