BENZOSEMIQUINONE

Base Information

• Chemical Name: BENZOSEMIQUINONE
• CAS No.: 3225-30-7
• Molecular Formula: C6H5O2
• Molecular Weight: 109.105

Synonyms:4-hydroxy-phenyloxyl;4-Hydroxy-phenoxyl;hydroquinone radical;semiquinone radical;Benzosemichinon-1,4-radikal;4-Hydroxy-phenoxy-radikal;

Chemical Property of BENZOSEMIQUINONE

Chemical Property:

• PSA: 37.30000
• LogP: -0.08060

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of BENZOSEMIQUINONE

There total 41 articles about BENZOSEMIQUINONE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.1%

α-(4-Hydroxyphenoxy)acetophenone (123540-69-2) → 2-(4-hydroxyphenyl)-1-phenylethan-1-one (6420-90-2) + 2-oxo-2-phenyl-ethyl (50781-28-7) + hydroquinone radical (3225-30-7) + acetophenone (98-86-2) + hydroquinone (123-31-9,8027-02-9) + phenacylacetophenone (495-71-6)

Guidance literature:

thiophenol; In benzene; Product distribution; Quantum yield; Kinetics; Irradiation;

DOI:10.1021/jo00288a019

Reference yield:

α-hydroxybenzyl radical (2406-15-7) + p-benzoquinone (106-51-4) → hydroquinone radical (3225-30-7) + benzaldehyde (100-52-7)

Guidance literature:

Thermodynamic data; Mechanism; ΔE(excit.), ΔH, other ketyl radicals, other carbonyl compounds;

DOI:10.1007/BF02494263

Reference yield:

CH3I(1+)*CHCl3*Cl(1-) + hydroquinone (123-31-9,8027-02-9) → chloroform (67-66-3,8013-54-5) + hydroquinone radical (3225-30-7) + methyl iodide (74-88-4)

Guidance literature:

In chloroform; at 22 ℃; Rate constant; multistep reaction;

DOI:10.1021/j100164a045

upstream raw materials:

hydroquinone

1,4-benzoquinone protonated anion

α-(4-Hydroxyphenoxy)acetophenone

O-protonated para-benzoquinone

Downstream raw materials:

hydroquinone

p-benzoquinone

C₇H₈NO

4-(N,N-dimethylamino)phenoxyl radical

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