Phosphorimidic triamide, N,N,N',N',N'',N''-hexamethyl-N'''-phenyl-

Base Information

• Chemical Name: Phosphorimidic triamide, N,N,N',N',N'',N''-hexamethyl-N'''-phenyl-
• CAS No.: 35589-04-9
• Molecular Formula: C12H23N4P
• Molecular Weight: 254.315
• DSSTox Substance ID: DTXSID40455893
• Nikkaji Number: J1.470.042K
• Wikidata: Q82278050
• Mol file: 35589-04-9.mol

Synonyms:phenylphosphazene;35589-04-9;Phosphorimidic triamide, N,N,N',N',N'',N''-hexamethyl-N'''-phenyl-;SCHEMBL13967872;DTXSID40455893;N-Phenyltris(dimethylamino)phosphine imide

Chemical Property of Phosphorimidic triamide, N,N,N',N',N'',N''-hexamethyl-N'''-phenyl-

Chemical Property:

• Melting Point: 11.5 °C
• Boiling Point: 127 °C(Press: 0.4 Torr)
• PSA: 31.89000
• Density: 1.054 g/cm3(Temp: 22 °C)
• LogP: 2.94910
• XLogP3: 2.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 254.16603375
• Heavy Atom Count: 17
• Complexity: 252

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(C)P(=NC1=CC=CC=C1)(N(C)C)N(C)C

Technology Process of Phosphorimidic triamide, N,N,N',N',N'',N''-hexamethyl-N'''-phenyl-

There total 4 articles about Phosphorimidic triamide, N,N,N',N',N'',N''-hexamethyl-N'''-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

Phenyl azide (622-37-7) + Hexamethylphosphorous triamide (1608-26-0) → (phenylimino)tris(dimethylamino)phosohazene (35589-04-9)

Guidance literature:

In benzene; for 10h; Heating;

DOI:10.1021/ja00065a009

Reference yield: 70.0%

bis-(dimethylamino)methane (51-80-9) + 2,2,2,4,4,4-hexachloro-1,3-diphenyl-1,3,2,4-diazadiphosphetidine → (phenylimino)tris(dimethylamino)phosohazene (35589-04-9) + dimethylamidodichlorophosphazobenzene (25605-02-1) + N,N,N',N'-tetramethyl-N''-phenylphosphorodiamidimidic chloride (19946-85-1)

Guidance literature:

In 1,2-dichloro-ethane; for 0.5h; Heating;

Reference yield:

Hexamethylphosphorous triamide (1608-26-0) → (phenylimino)tris(dimethylamino)phosohazene (35589-04-9)

Guidance literature:

Multi-step reaction with 2 steps

1: diethyl ether

2: (thermolysis)

In diethyl ether;

DOI:10.1039/DT9750000016

upstream raw materials:

C₁₂H₂₃N₆P

Phenyl azide

Hexamethylphosphorous triamide

bis-(dimethylamino)methane