756-13-8Relevant articles and documents
Method for synthesizing perfluoro(2-methyl-3-pentanone)
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Paragraph 0015; 0032-0075, (2020/04/22)
The invention discloses a method for synthesizing perfluoro(2-methyl-3-pentanone). The method comprises the following steps: in the presence of a polar aprotic solvent, carrying out an isomerization synthesis reaction in a micro-channel reactor by taking perfluoro-2,3-epoxy-2-methylpentane as a raw material and using an organic amine or metal fluoride as a catalyst to obtain a reaction product, and sequentially carrying out standing separation and rectification treatment on the reaction product to obtain perfluoro(2-methyl-3-pentanone). According to the invention, a reaction is performed by using a micro-channel reactor, so that the whole isomerization synthesis reaction cannot contact water or water vapor so as to avoid the generation of by-products and improve the conversion rate and theyield of the perfluoro(2-methyl-3-pentanone); and raw materials and a catalyst are subjected to high-speed uniform mixing and heat and mass transfer in the micro-channel reactor, so that the rate ofthe synthesis reaction is increased, the continuous and efficient synthesis of perfluoro(2-methyl-3-pentanone) is realized, and the method is good in repeatability, rapid in system response, easy forautomatic control and amplified production, almost free of amplification effect, high in safety, less in three wastes and easy for industrial production.
Method for preparing pentafluoride ethyl perfluoro isopropyl ketone through gas phases
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Paragraph 0055-0056, (2018/08/03)
The invention discloses a method for preparing pentafluoride ethyl perfluoro isopropyl ketone through gas phases. The method is characterized in that under the existence of addition catalysts, hexafluoropropylene and hexafluoropropylene oxide or pentafluoropropionyl fluoride take gas phase addition reaction to obtain the pentafluoride ethyl perfluoro isopropyl ketone, or tetrafluoroethylene and heptafluorobutyl fluoride take gas phase addition reaction to obtain the pentafluoride ethyl perfluoro isopropyl ketone. The method has the advantages that the reaction route is short; in addition, rawmaterials such as the hexafluoropropylene, the tetrafluoroethylene, the hexafluoropropylene oxide and carbonyl fluoride can be easily obtained; the cost is low; the yield of the pentafluoride ethyl perfluoro isopropyl ketone is high; the continuous large-scale industrial production can be realized through the route.
Method for preparing perfluoro ethyl isopropylacetone
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, (2017/01/19)
The invention provides a preparation method of perfluorethyl isopropyl ketone. The preparation method specifically comprises the step of: with a hexafluoropropylene dipolymer mixture and perfluo-4-methyl-2-amylene or perfluo-2-methyl-2-amylene as raw materials, carrying out reaction processes such as olefin epoxidation, structural rearrangement of epoxide to prepare the perfluorethyl isopropyl ketone. An aprotic polar solvent, a catalyst and a phase transfer catalyst are used in a preparation process, high selectivity and high transformation rate of all steps of reactions are realized, and after a reaction mixture is simply separated so that an intermediate and a perfluorethyl isopropyl ketone product with high quality can be obtained. Meanwhile, a one-pot technology of double bond isomerization and epoxidation reaction is established. The preparation method provided by the invention has the characteristics that raw materials are easily available, the cost is low, reaction conditions are mild, operation is safe and simple, reaction selectivity and transformation rate are high, little environment influence is low; therefore, the preparation method is suitable for industrial application.