RUBIDIUM IODATE

Base Information

• Chemical Name: RUBIDIUM IODATE
• CAS No.: 13446-76-9
• Molecular Formula: HI O3 . Rb
• Molecular Weight: 260.37
• Mol file: 13446-76-9.mol

Synonyms:Iodic acid(HIO3), rubidium salt (8CI,9CI); Rubidium iodate (RbIO3) (6CI,7CI); Rubidiumiodate; Rubidium iodine oxide (RbIO3)

Chemical Property of RUBIDIUM IODATE

Chemical Property:

• PSA: 57.20000
• LogP: 0.52930

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of RUBIDIUM IODATE

There total 14 articles about RUBIDIUM IODATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

rubidium carbonate + iodic acid (7782-68-5) → rubidium iodate (13446-76-9)

Guidance literature:

In water; at 230 ℃; for 83h; Autoclave;

DOI:10.1021/acs.chemmater.5b04511

Reference yield: 90.0%

rubidium periodate (13465-48-0) + molybdenum(VI) oxide → rubidium iodate (13446-76-9) + RbMoO3(IO3)

Guidance literature:

With water; In water; MoO3 and RbIO4 were loaded in Parr 4749 PTFE-lined autoclave, water was added, the mixt. was heated for 3 d at 180°C; the autoclave was cooled at a rate of 9°C/h to 23°C, the mother liquors were decanted from crystalline products that were subsequently washed with methanol, the colorless plates of RbMoO3(IO3) were sepd. from colorless cubes of RbIO3;

DOI:10.1021/ja012190z

Reference yield: 20.0%

rubidium carbonate + indium(III) oxide + periodic acid (10450-60-9) → indium(III) iodate + rubidium iodate (13446-76-9) + 3Rb(1+)*In(IO3)6(3-)=Rb3In(IO3)6

Guidance literature:

In water; High Pressure; under hydrothermal conditions; mixt. of Rb2CO3, In2O3 and H5IO6 in H2O sealed in autoclave; heated at 200°C for 4 d; cooled slowly to room temp. (6°C/h); initial and final pH are 0.6 and 0.7; satisfactory elem. anal.;

DOI:10.1039/c0dt01272f

upstream raw materials:

hydriodic acid

rubidium chloride

iodic acid

iodine trichloride

Downstream raw materials:

rubidium dichloroiodate(I)

chlorine

iodine trichloride

Refernces

• 1、 Sykora, Richard E.,Kang, Min Ok,Halasyamani, P. Shiv,Albrecht-Schmitt, Thomas E.. "Structural modulation of molybdenyl iodate architectures by alkali metal cations in AMoO3(IO3) (A = K, RB, Cs): A facile route to new polar materials with large SHG responses". . p. 1951 - 1957. Retrieved 2002.
• 2、 Ok, Kang Min,Halasyamani, P. Shiv. "The lone-pair cation I5+ in a hexagonal tungsten oxide-like framework: Synthesis, structure, and second-harmonic generating properties of Cs2I4O11". . p. 5489 - 5491. Retrieved 2004.
• 3、 Wu, Qi,Liu, Hongming,Jiang, Fangchao,Kang, Lei,Yang, Lei,Lin, Zheshuai,Hu, Zhanggui,Chen, Xingguo,Meng, Xianggao,Qin, Jingui. "RbIO3 and RbIO2F2: Two Promising Nonlinear Optical Materials in Mid-IR Region and Influence of Partially Replacing Oxygen with Fluorine for Improving Laser Damage Threshold". . p. 1413 - 1418. Retrieved 2016.